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2023 , Vol. 43 >Issue 7: 2447 - 2453

DOI: https://doi.org/10.6023/cjoc202210006

研究论文

联吡啶配体促进铬催化炔烃的顺式硼氢化反应

  • 王莎 ,
  • 陈常鹏 ,
  • 曾小明
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  • 四川大学化学学院 成都 610064

收稿日期: 2023-05-20

  修回日期: 2023-06-06

  网络出版日期: 2023-06-14

基金资助

国家自然科学基金(21971168); 国家自然科学基金(22125107)

收起

Bipyridine Ligand-Promoted cis-Selective Hydroboration of Alkynes with Chromium Catalysis

  • Sha Wang ,
  • Changpeng Chen ,
  • Xiaoming Zeng
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  • College of Chemistry, Sichuan University, Chengdu 610064
*E-mail:

Received date: 2023-05-20

  Revised date: 2023-06-06

  Online published: 2023-06-14

Supported by

National Natural Science Foundation of China(21971168); National Natural Science Foundation of China(22125107)

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摘要

报道了金属铬催化炔烃的硼氢化反应. 廉价易得的三氯化铬在4,4'-二叔丁基-2,2'-联吡啶配体及单质镁的还原作用下表现出高反应活性, 催化实现了频哪醇硼烷与炔烃加成的硼氢化反应, 为室温条件下制备烯基硼化合物提供了一条有效的合成策略.

关键词： 铬催化; 硼氢化反应

本文引用格式

王莎 , 陈常鹏 , 曾小明 . 联吡啶配体促进铬催化炔烃的顺式硼氢化反应[J]. 有机化学, 2023 , 43(7) : 2447 -2453 . DOI: 10.6023/cjoc202210006

Abstract

The chromium-catalyzed hydroboration of alkynes under mild conditions was reported. Low-cost chromium(III) chloride combined with 4,4'-di-tert-butyl 2,2'-bipyridine as the ligand and magnesium as the reductant shows high reactivity, which can catalyze and promote the hydroboration of alkynes with pinacolborane, thereby providing a strategy to form borylated olefins at ambient temperature.

Key words： chromium catalysis; hydroboration

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