不对称傅-克反应在构建手性3-取代吲哚中的研究进展
收稿日期: 2023-03-05
修回日期: 2023-06-04
网络出版日期: 2023-07-20
基金资助
北京林业大学“卓越实验师”培育专项基金(20210902)
Recent Progress in the Construction of Chiral 3-Substituted Indoles by Asymmetric Friedel-Crafts Reactions
Received date: 2023-03-05
Revised date: 2023-06-04
Online published: 2023-07-20
Supported by
Excellent Laboratory Teacher Cultivation Program of Beijing Forestry University(20210902)
刘甜甜 , 段新红 . 不对称傅-克反应在构建手性3-取代吲哚中的研究进展[J]. 有机化学, 2023 , 43(11) : 3695 -3712 . DOI: 10.6023/cjoc202303010
Chiral C(3)-functionalized indoles have received much attention as strategic building blocks for the synthesis of many natural products and bioactive compounds. Particularly in the past twenty years, application of chiral metal complexes and small-molecule organocatalysts for the asymmetric Friedel-Crafts C(3)-alkylations of indoles has become a hot topic in the organic field. Applications of asymmetric Friedel-Crafts reactions in the synthesis of C(3)-substituted indoles are reviewed according to the catalysts that promoting reaction. Moreover, future perspectives are also presented.
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