B(C6F5)3催化不饱和烃的硅化反应
收稿日期: 2023-06-12
修回日期: 2023-07-22
网络出版日期: 2023-08-15
基金资助
国家自然科学基金(21825108)
B(C6F5)3-Catalyzed Silylation of Unsaturated Hydrocarbons
Received date: 2023-06-12
Revised date: 2023-07-22
Online published: 2023-08-15
Supported by
National Natural Science Foundation of China(21825108)
冯向青 , 杜海峰 . B(C6F5)3催化不饱和烃的硅化反应[J]. 有机化学, 2023 , 43(10) : 3544 -3557 . DOI: 10.6023/cjoc202306009
Organosilicon compounds have been widely applied in synthetic chemistry, medicinal chemistry, polymer chemistry, organic photoelectric materials and other fields due to their unique properties. The silylation of unsaturated compounds represents one of the most important approaches for the synthesis of organosilicon compounds, which has attracted the intensive attention of chemists, and a great success has been achieved. As a unique non-metallic Lewis acid, B(C6F5)3-catalyzed silylation of unsaturated compounds has made a significant progress in recent years. This subject and the corresponding mechanism are demonstrated.
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