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2023 , Vol. 43 >Issue 12: 4036 - 4056

DOI: https://doi.org/10.6023/cjoc202305012

综述与进展

可见光诱导有机膦促进脱氧官能化反应研究进展

  • 汤娟 ,
  • 胡家榆 ,
  • 祝志强 ,
  • 蒲守智
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  • a 江西科技师范大学 江西省有机功能分子重点实验室 南昌 330038
    b 江西师范大学 江西省绿色化学重点实验室 南昌 330022
    c 东华理工大学 江西省合成化学重点实验室 南昌 330013

收稿日期: 2023-05-11

  修回日期: 2023-07-06

  网络出版日期: 2023-08-30

基金资助

国家自然科学基金(21864013); 国家自然科学基金(22263005); 江西省自然科学基金(20212BCJL23057); 江西省自然科学基金(20224ACB203006); 江西省自然科学基金(20232BAB203001); 江西省博士后基金(2019KY40)

收起

Recent Advances in Visible-Light-Induced Organic Phosphine- Promoted Deoxygenative Functionalization Reactions

  • Juan Tang ,
  • Jiayu Hu ,
  • Zhiqiang Zhu ,
  • Shouzhi Pu
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  • a Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013
    b Key Laboratory for Green Chemistry of Jiangxi Province, Jiangxi Normal University, Nanchang 330022
    c Jiangxi Province Key Laboratory of Synthetic Chemistry, East China University of Technology, Nanchang 330013
*E-mail: ;

Received date: 2023-05-11

  Revised date: 2023-07-06

  Online published: 2023-08-30

Supported by

National Natural Science Foundation of China(21864013); National Natural Science Foundation of China(22263005); Natural Science Foundation of Jiangxi Province(20212BCJL23057); Natural Science Foundation of Jiangxi Province(20224ACB203006); Natural Science Foundation of Jiangxi Province(20232BAB203001); Postdoctoral Foundation of Jiangxi Province(2019KY40)

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摘要

脱氧偶联反应是有机化学中的重要合成转化, 有机膦促进的有机合成反应近年来发展迅速, 三苯基膦及其衍生物是有机膦中重要的一类, 其在有机合成反应中不仅可以作为配体, 而且可以用作脱氧促进剂. 最近几年, 可见光诱导有机膦促进脱氧偶联反应受到研究者们广泛关注, 该类型反应利用有机膦在可见光下经单电子转移后与含氧有机分子形成P—O中间体, 随后经脱氧得到高活性自由基物种, 并最终完成脱氧偶联, 反应底物无需预先官能团化且条件温和. 系统地概述了近年来光氧化还原诱导下有机膦促进含氧有机分子脱氧官能化反应的研究进展.

关键词： 可见光; 有机膦; 脱氧; 自由基; 官能化

本文引用格式

汤娟 , 胡家榆 , 祝志强 , 蒲守智 . 可见光诱导有机膦促进脱氧官能化反应研究进展[J]. 有机化学, 2023 , 43(12) : 4036 -4056 . DOI: 10.6023/cjoc202305012

Abstract

Organic phosphine-promoted organic synthesis reactions have developed rapidly in recent years. Triphenylphos- phine and their derivatives are the most important class of organic phosphine compounds, which can not only serve as ligands in organic synthesis reactions, but also serve as deoxygenative promoters in a large number of reactions. In recent years, visible-light-induced deoxygenative coupling reactions have aroused considerable attention. This type of reaction uses organic phosphines to promote single electron transfer to form P—O intermediates with oxygen-containing organic molecules under visible-light, followed by deoxidation to obtain highly active free radical species, and then deoxygenative coupling to afford the desired products. Herein, the recent research progress in photoredox-induced organic phosphine-promoted deoxygenative functionalization reactions is summarized.

Key words： visible-light; organic phosphine; deoxygenation; free radical; functionalization

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