巢式-碳硼烷硼氢键官能化反应研究进展
收稿日期: 2023-07-10
修回日期: 2023-09-14
网络出版日期: 2023-10-26
基金资助
国家自然科学基金(22161015); 海南省自然科学基金(221RC448)
Recent Progress in B—H Bond Functionalization of nido-Carboranes
Received date: 2023-07-10
Revised date: 2023-09-14
Online published: 2023-10-26
Supported by
National Natural Science Foundation of China(22161015); Hainan Provincial Natural Science Foundation of China(221RC448)
付雅彤 , 孙超凡 , 张丹 , 金成国 , 陆居有 . 巢式-碳硼烷硼氢键官能化反应研究进展[J]. 有机化学, 2024 , 44(2) : 438 -447 . DOI: 10.6023/cjoc202307006
nido-Carboranes are versatile building blocks in medicine, materials science, and organometallic/coordination chemistry. Recently, direct B—H activation and functionalization of nido-carboranes have received much attention. Achieving regioselectivity in polyhedral cage B—H activation among ten chemically similar B—H vertices is a long-standing challenge in carborane chemistry. In this context, the activation of exo-cage B—H vertices on the open C2B3 pentagonal plane of nido-carboranes has been extensively studied. However, few direct activation reactions of B—H vertices that are located on the closed polyhedral sphere in nido-carborane have been reported. The recent progress on the regioselective B—H bond functionalization reaction of nido-carboranes is summarized. This topic is categorized into open plane exo-B—H activation and polyhedral sphere B—H activation.
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