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2024 , Vol. 44 >Issue 3: 966 - 971

DOI: https://doi.org/10.6023/cjoc202310029

研究论文

以路易斯碱硼烷为氢供体电催化还原喹啉及酮

  • 陈红斌 ,
  • 杨思佳 ,
  • 叶智鹏 ,
  • 陈凯 ,
  • 向皞月 ,
  • 阳华
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  • 中南大学化学化工学院 长沙 410083
共同第一作者

收稿日期: 2023-10-30

  修回日期: 2023-12-28

  网络出版日期: 2024-01-12

基金资助

国家自然科学基金(22078370); 国家自然科学基金(22078369); 国家自然科学基金(22003077); 国家自然科学基金基础科学中心项目(72088101); 湖南省自然科学基金(2022JJ20055); 湖南省自然科学基金(2020JJ4682)

收起

Electrocatalytic Reduction of Quinolines and Ketones by Using Lewis Base-Ligated Borane as a Hydrogen Donor

  • Hongbing Chen ,
  • Sijia Yang ,
  • Zhipeng Ye ,
  • Kai Chen ,
  • Haoyue Xiang ,
  • Hua Yang
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  • College of Chemistry and Chemical Engineering, Central South University, Changsha 410083
These authors contributed equally to this work.
*E-mail: ;
;

Received date: 2023-10-30

  Revised date: 2023-12-28

  Online published: 2024-01-12

Supported by

National Natural Science Foundation of China(22078370); National Natural Science Foundation of China(22078369); National Natural Science Foundation of China(22003077); Basic Science Center Project for National Natural Science Foundation of China(72088101); Natural Science Foundation of Hunan Province(2022JJ20055); Natural Science Foundation of Hunan Province(2020JJ4682)

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摘要

以路易斯碱-硼烷络合物(LB-BH3)为氢供体, 开发了一种通用的、直接的喹啉电化学还原策略, 从而快速获得多种具有生物活性的1,2,3,4-四氢喹啉类化合物. 此外, 该方法还被成功地应用于其他双键的还原, 包括C=O, N=N和 C=C. 该方法具有操作简单、反应条件温和及底物范围广等特点.

关键词： 硼烷; 电化学; 还原; 1,2,3,4-四氢喹啉类

本文引用格式

陈红斌 , 杨思佳 , 叶智鹏 , 陈凯 , 向皞月 , 阳华 . 以路易斯碱硼烷为氢供体电催化还原喹啉及酮[J]. 有机化学, 2024 , 44(3) : 966 -971 . DOI: 10.6023/cjoc202310029

Abstract

By employing Lewis base-ligated boranes (LB-BH3) as the hydrogen donor, a general and straightforward electrochemical protocol for transfer hydrogenation of quinoline was developed to access a variety of bioactive 1,2,3,4- tetrahydroquinolines. Moreover, this developed protocol was successfully applied to the reduction of other double bonds, including C=O, N=N and C=C bonds. This method has some characteristics such as simple operation, mild reaction conditions and a wide range of substrates.

Key words： borane; electrochemistry; reduction; 1,2,3,4-tetrahydroquinoline

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