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DOI: https://doi.org/10.6023/cjoc202509022

综述与进展

手性有机硒化合物的合成研究进展

  • 郭艳辉 ,
  • 屈红恩 ,
  • 梁佩
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  • 赣南科技学院 江西省教育厅钨稀土资源智能绿色开发重点实验室 江西 赣州 341000

收稿日期: 2025-10-15

  修回日期: 2025-11-07

  网络出版日期: 2025-12-10

基金资助

赣南科技学院科研启动项目(No.0310203)和赣南科技学院学术带头人(No.2025033)资助项目.

收起

Recent advances in synthesis of chiral organoselenium compounds

  • Guo Yanhui ,
  • Qu Hongen ,
  • Liang Pei
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  • Key Laboratory of Intelligent and Green Development of Tungsten & Rare Earth Resources, Jiangxi Provincial Department of Education, Gannan University of Science and Technology, Ganzhou Jiangxi, 341000

Received date: 2025-10-15

  Revised date: 2025-11-07

  Online published: 2025-12-10

Supported by

Gannan University of Science and Technology Research Launch Project (No. 0310203) and the Academic leader of Gannan University of Science and Technology (No. 2025033).

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摘要

手性有机硒化合物广泛存在于活性生物分子、天然产物、药物分子和功能材料等领域中, 同时也是有机合成中重要的中间体和催化剂. 基于此类化合物的重要作用, 手性有机硒化合物的合成一直是有机化学方向热点研究领域之一. 近年来, 发展绿色经济的手性有机硒化合物合成方法吸引了广泛得到关注. 本文主要综述了近十年基于不同催化体系下合成手性有机硒化合物的研究进展, 主要分为无金属催化、金属催化、光催化三种反应体系来归纳总结, 并对手性有机硒化合物合成的挑战和未来发展方向进行了探讨.

关键词： 无金属催化; 金属催化; 光催化; 手性有机硒化合物

本文引用格式

郭艳辉 , 屈红恩 , 梁佩 . 手性有机硒化合物的合成研究进展[J]. 有机化学, 0 : 9022 . DOI: 10.6023/cjoc202509022

Abstract

Chiral organoselenium compounds are widely found in bioactive molecules, natural products, pharmaceutical agents, and functional materials. They also serve as important intermediates and catalysts in organic synthesis. Given the significance of such compounds, the synthesis of chiral organoselenium compounds has long been a hot research topic in organic chemistry. In recent years, the development of environmentally benign and cost-effective methods for synthesizing chiral organoselenium compounds has attracted considerable attention. This article reviews the research progress in the synthesis of chiral organoselenium compounds under different catalytic systems over the past decade. This review is organized into three catalytic systems: metal-free catalysis, metal catalysis, and photocatalysis, and the research progress of each system is discussed in detail. Additionally, the challenges and future directions in the synthesis of chiral organoselenium compounds are also discussed.

Key words： Metal-free catalysis; metal-catalysis; photocatalysis; chiral organoselenium compounds

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