Supramolecular Catalysis of Cucurbit[8]uril on Photocycloaddition of 1,ω-Bi(2-aminopyridinium)alkylates

doi:10.6023/cjoc1109211

Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (06): 1093-1100.DOI: 10.6023/cjoc1109211 Previous Articles Next Articles

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八元瓜环对1,ω-二(2-氨基吡啶)烷烃光致环加成反应的超分子催化性能的研究

丛航^a, 王杞生^a, 张建新^a,b, 陶朱^a, 薛赛凤^a

a 贵州大学应用化学研究所贵阳 550002;
b 贵州省天然产物重点实验室贵阳 550003

收稿日期:2011-09-21 修回日期:2012-01-11 发布日期:2012-02-22
通讯作者: 张建新 E-mail:ecnuc@163.com
基金资助:
国家自然科学基金(No. 21162003)、贵州省科学技术基金(Nos. 黔科合J 字[2008]75, [2009]2073 及[2010]2126 号)资助项目.

Supramolecular Catalysis of Cucurbit[8]uril on Photocycloaddition of 1,ω-Bi(2-aminopyridinium)alkylates

Cong Hang^a, Wang Qisheng^a, Zhang Jianxin^a,b, Tao Zhu^a, Xue Saifeng^a

a Institute of Applied Chemistry, Guizhou University, Guiyang 550002;
b Key Laboratory of Chemistry for Natural Products of Guizhou Province, Guiyang 550003

Received:2011-09-21 Revised:2012-01-11 Published:2012-02-22
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21162003), the Natural Science Foundation of Guizhou Province (Nos. [2008]75, [2009]2073, [2010]2126).

Three kinds of 1,ω-bi(2-aminopyridinium)alkylates, which are the 1,4-bi(2-aminopyridinium)butane dibromide (C4), 1,6-bi(2-aminopyridinium)hexane dibromide (C6) and 1,8-bi(2-aminopyridinium)octane dibromide (C8), have been synthesized, respectively. The host-guest interactions of cucurbit[8]uril (Q[8]) with the above compounds have been investigated using ¹H NMR and UV-vis spectra, and the results showed that there were different interaction models in the three host-guest systems. Subsequently, the photocycloaddition reactions of the substrates have been carried out in the presence of Q[8], and the dependence of the supramolecular catalytic active on the construction of substrate was observed.

Key words: 1,ω-bi(2-aminopyridinium)alkylates, cucurbituril, photocycloaddition, host-guest interaction, supramolecular catalysis

Cite this article

Cong Hang, Wang Qisheng, Zhang Jianxin, Tao Zhu, Xue Saifeng. Supramolecular Catalysis of Cucurbit[8]uril on Photocycloaddition of 1,ω-Bi(2-aminopyridinium)alkylates[J]. Chin. J. Org. Chem., 2012, 32(06): 1093-1100.

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八元瓜环对1,ω-二(2-氨基吡啶)烷烃光致环加成反应的超分子催化性能的研究

Supramolecular Catalysis of Cucurbit[8]uril on Photocycloaddition of 1,ω-Bi(2-aminopyridinium)alkylates

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