A Novel Silver(I)-Catalyzed Reaction of Terminal Arylacetylenes with Sulfonyl Chlorides

doi:10.6023/cjoc201204011

Abstract

A novel reaction of terminal arylacetylenes with sulfonyl chlorides was performed in the presence of a silver(I) catalyst. Vinyl sulfones were obtained in 47%～72% yields. A free radical mechanism for the catalytic cycle has been proposed to account for the formation of products and the stereochemical outcome of vinyl sulfones.

Key words: alkynes, sulfonyl chlorides, vinyl sulfones, silver salt, alkynyl silver

Cite this article

Deng Guisheng, Sun Tengfei, Zhou Jia. A Novel Silver(I)-Catalyzed Reaction of Terminal Arylacetylenes with Sulfonyl Chlorides[J]. Chin. J. Org. Chem., 2012, 32(10): 1872-1879.

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