Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (12): 4267-4273.DOI: 10.6023/cjoc202006025 Previous Articles     Next Articles

Special Issue: 有机光催化虚拟合辑


陈德茂, 孙媛媛, 董道青, 韩晴晴, 王祖利   

  1. 青岛农业大学化学与药学院 山东青岛 266109
  • 收稿日期:2020-06-15 修回日期:2020-07-29 发布日期:2020-08-06
  • 通讯作者: 王祖利
  • 基金资助:

Visible-Light Induced Sulfonylation of Nitroolefins for the Synthesis of Vinyl Sulfones under Photocatalyst Free Conditions

Chen Demao, Sun Yuanyuan, Dong Daoqing, Han Qingqing, Wang Zuli   

  1. College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao, Shandong 266109
  • Received:2020-06-15 Revised:2020-07-29 Published:2020-08-06
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 21772107), and the Key Research and Development Plan of Shandong Province (No. 2019GSF108017).

An eco-friendly visible light-induced approach for the synthesis of vinyl sulfones from the reaction of nitroolefins with sulfinic acid under photocatalyst free conditions was developed. Simple operation, mild reaction conditions, broad substrate scope and good yields of the desired products made this transformation have an excellent prospect. The anti-microbial activity test showed that some of the desired products had moderate inhibitory rate against V. mali and C. glecosporioides.

Key words: visible light, vinyl sulfones, nitroolefins, sulfinic acid