Microwave-Assisted Synthesis of Arene Ru(II) Complexes[(η6-RC6H5)Ru(m-MOPIP)Cl]Cl

doi:10.6023/cjoc201303022

Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (9): 2022-2027.DOI: 10.6023/cjoc201303022 Previous Articles Next Articles

Notes

微波辅助合成芳烃钌(II)配合物[(η⁶-RC₆H₅)Ru(m-MOPIP)Cl]Cl

吴琼^a, 吴剑^a, 梅文杰^a, 姚骏骅^b, 吴韦黎^a, 陈燕华^a, 陶韵伊^a

a 广东药学院药科学院广州 510006;
b 中山大学测试中心广州 510275

收稿日期:2013-03-15 修回日期:2013-04-06 发布日期:2013-05-06
通讯作者: 梅文杰 E-mail:weijiemei@126.com
基金资助:
广东省科技计划(No. 2013J4100072);广州市科技计划(No. 7411791521750)资助项目

Microwave-Assisted Synthesis of Arene Ru(II) Complexes[(η⁶-RC₆H₅)Ru(m-MOPIP)Cl]Cl

Wu Qiong^a, Wu Jian^a, Mei Wenjie^a, Yao Junhua^b, Wu Weili^a, Chen Yanhua^a, Tao Yunyi^a

a School of Pharmacy, Guangdong Pharmaceutical University, Gongzhou 510006;
b Instrumental Analysis and Research Center, Sun Yat-sen University, Gongzhou 510275

Received:2013-03-15 Revised:2013-04-06 Published:2013-05-06
Supported by:
Project supported by the Science and Technology Planning Project of Guangdong Province (No. 2013J4100072) and the Science and Technology Planning Project of Guangzhou City (No. 7411791521750)

Two arene Ru(II) complexes[(η⁶-RC₆H₅)Ru(m-MOPIP)Cl]⁺ (R=H 3a, R=CH₃ 3b; m-MOPIP=2-(3-meth- oxyphenyl)imidazole[4,5-f][1,10]phenanthroline) were prepared under the microwave irradiation at 60 ℃ for 30 min in Pyrex vessel with the yield of about 90% and 91%, and the target compounds were characterized by ¹H NMR,¹³C NMR, IR, ESI-MS and ¹H-¹H COSY spectra. At the same reaction conditions, application of SiC vessel to screen the effect of microwave irradiation, 3a and 3b were obtained with the yield of about 89% and 90%. These results indicated that the microwave "non-thermal effect" has no obvious influence on the synthesis of arene Ru(II) complexes.

Key words: microwave-assisted synthesis, 2-(3-methoxyphenyl)imidazole[4,5f][1,10]phenanthroline, arene Ru(II) complexes

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Wu Qiong, Wu Jian, Mei Wenjie, Yao Junhua, Wu Weili, Chen Yanhua, Tao Yunyi. Microwave-Assisted Synthesis of Arene Ru(II) Complexes[(η⁶-RC₆H₅)Ru(m-MOPIP)Cl]Cl[J]. Chin. J. Org. Chem., 2013, 33(9): 2022-2027.

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微波辅助合成芳烃钌(II)配合物[(η⁶-RC₆H₅)Ru(m-MOPIP)Cl]Cl

Microwave-Assisted Synthesis of Arene Ru(II) Complexes[(η⁶-RC₆H₅)Ru(m-MOPIP)Cl]Cl

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微波辅助合成芳烃钌(II)配合物[(η6-RC6H5)Ru(m-MOPIP)Cl]Cl