Preparation of Hydrophobic SiO2 Aerogel by Rapid Solvents Exchange Method and Its Application Loaded with Organic Fluorescence Probe

doi:10.6023/cjoc201808002

Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (2): 550-554.DOI: 10.6023/cjoc201808002 Previous Articles Next Articles

Special Issue: 荧光探针-生物传感合辑；有机超分子化学合辑；有机硅化学虚拟合辑

Notes

快速溶剂交换法制备疏水性二氧化硅气凝胶及其负载有机荧光探针的应用研究

王亚飞^a, 张涛^a,b, 郭旭东^a, 胡睿^a, 王双青^a, 杨国强^a

a 中国科学院化学研究所光化学重点实验室中国科学院大学北京 100190;
b 中国科学院深圳先进技术研究院先进材料中心深圳 518055

收稿日期:2018-08-05 修回日期:2018-09-06 发布日期:2018-09-26
通讯作者: 王双青, 杨国强 E-mail:g1704@iccas.ac.cn;gqyang@iccas.ac.cn
基金资助:
国家自然科学基金（Nos.21873106，21627802）资助项目.

Preparation of Hydrophobic SiO₂ Aerogel by Rapid Solvents Exchange Method and Its Application Loaded with Organic Fluorescence Probe

Wang Yafei^a, Zhang Tao^a,b, Guo Xudong^a, Hu Rui^a, Wang Shuangqing^a, Yang Guoqiang^a

a Key Laboratory of Photochemistry, Institute of Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190;
b Center of Advanced Material Research, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055

Received:2018-08-05 Revised:2018-09-06 Published:2018-09-26
Contact: 10.6023/cjoc201808002 E-mail:g1704@iccas.ac.cn;gqyang@iccas.ac.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21873106, 21627802).

1. Preparation of Hydrophobic SiO₂ Aerogel by Rapid Solvents Exchange Method and Its Application Loaded with Organic Fluorescence Probe.PDF(302KB)

Abstract

Aerogel is a kind of gel materials, of which the fluid phase is gas. Aerogel has the characteristics of low density and high porosity, and has a wide application prospects. In this work, a rapid solvents exchange method was developed, and using in-situ secondary extraction, rapid solvents exchange in aerogel preparation was achieved through the miscibility and immiscibility of ethanol-dichloromethane-water. Combined with hydrophobic treatment and vacuum drying, hydrophobic silica aerogel was obtained. The aerogel had a low density and a contact angle with water of 155.8°. The aerogel can load various organic fluorescent probe dyes, which can effectively avoid the fluorescence quenching caused by the aggregation of the probe molecules, which it will expand the practical application range of the organic fluorescent probes in wider fields.

Key words: aerogel, organic fluorescence probe, preparation, rapid solvents exchange method, application

Cite this article

Wang Yafei, Zhang Tao, Guo Xudong, Hu Rui, Wang Shuangqing, Yang Guoqiang. Preparation of Hydrophobic SiO₂ Aerogel by Rapid Solvents Exchange Method and Its Application Loaded with Organic Fluorescence Probe[J]. Chin. J. Org. Chem., 2019, 39(2): 550-554.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Wang, X. C.; Li, J. Z.; Li, G. Y.; Wang, J.; Zhang, X. T.; Guo, Q. Acta Phys.-Chim. Sin. 2017, 33, 2141(in Chinese). (王叙春, 李金泽, 李广勇, 王锦, 张学同, 郭强, 物理化学学报, 2017, 33, 2141.)
[2] Cuce, E.; Cuce, P. M.; Wood, C. J.; Riffat, S. B. Renewable Sustainable Energy Rev. 2014, 34, 273.
[3] Gurav, J. L.; Jung, I.-K.; Park, H.-H.; Kang, E. S.; Nadargi, D. Y. J. Nanomater. 2010, 409310.
[4] Aegerter, M. A.; Leventis, N.; Koebel, M. M. Aerogels Handbook, Springer, New York, 2011.
[5] Hüsing, N.; Schubert, U. Angew. Chem., Int. Ed. 1998, 37, 22.
[6] Jia, G. H; Li, Z; Liu, P; Jing, Q. S. J. Non-Cryst. Solids 2018, 482, 192.
[7] Wei, T.-Y.; Chang, T.-F.; Luw, S.-Y.; Chang, Y.-C. J. Am. Ceram. Soc. 2007, 90, 2003.
[8] Chen, Q. F.; Wang, H.; Sun, L. Y. Materials 2017, 10, 435.
[9] Feng, J.; Tian, K. J.; Hu, D. H.; Wang, S. Q.; Li, S. Y.; Zeng, Y.; Li, Y.; Yang, G. Q. Angew. Chem., Int. Ed. 2011, 50, 8072.
[10] Liu, J.; Guo, X. D.; Hu, R.; Xu, J.; Wang, S. Q.; Li, S. Y.; Li, Y.; Yang, G. Q. Anal. Chem. 2015, 87, 3694.
[11] Cao, L. X.; Li, X. Y.; Wang, S. Q.; Li, S. Y.; Li, Y.; Yang, G. Q. Chem. Commun. 2014, 50, 8787.
[12] Li, S.; Hu, R.; Yang, C. L.; Zhang, X.; Zeng, Y.; Wang, S. Q.; Guo, X. D.; Li, Y.; Cai, X. P.; Li, S. R.; Han, C. W.; Yang, G. Q. Biosens. Bioelectron. 2017, 98, 325.
[13] Hu, D. H.; Zhang, T.; Li. S. Y.; Yu, T. J.; Zhang, X. H.; Hu, R.; Feng, J.; Wang, S. Q.; Liang, T. L.; Chen, J. M.; Sobenina, L. N.; Trofimov, B. A.; Li, Y.; Ma, J. S.; Yang, G. Q. Nat. Commun. 2018, 9, 362.
[14] Kolanowski, J. L.; Liu, F.; New, E. J. Chem. Soc. Rev. 2018, 47, 195.
[15] Sinkeldam, R. W.; Greco, N. J. Tor, Y. Chem. Rev. 2010, 110, 2579.
[16] Zhao, Z. S.; Guo, X. D.; Li, S. Y.; Yang, G. Q. Acta Chim. Sinica 2016, 74, 593(in Chinese). (赵振盛, 郭旭东, 李沙瑜, 杨国强, 化学学报, 2016, 74, 593.)
[17] Xu, M. M.; Guo, C.; Hu, G. F.; Xu, S. Y.; Wang, L. Y. Chin. J. Chem. 2018, 36, 25.
[18] Yang, L. M.; Liu, B.; Li, N., Tang, B. Acta Chim. Sinica 2017, 75, 1047(in Chinese). (杨立敏, 刘波, 李娜, 唐波, 化学学报, 2017, 75, 1047.)
[19] Wang, S. J.; Li, C. W.; Li, J.; Chen, B.; Guo, Y. Acta Chim. Sinica 2017, 75, 383(in Chinese). (王少静, 李长伟, 李锦, 陈邦, 郭媛, 化学学报, 2017, 75, 383.)
[20] Theaker, B. J.; Hudson, K. E.; Rowell, F. J. Forensic Sci. Int. 2008, 174, 26.
[21] Domínguez, G.; Westphal, A. J.; Phillips, M. L. F.; Jones, S. M. Astrophys. J. 2003, 592, 631.
[22] Dantas, T. N. C.; Neto, A. A. D.; Moura, M. C. P. A.; Neto, E. L. B.; Forte, K. R; Leite, R. H. L. Water Res. 2003, 37, 2709.
[23] Yang, Y. Y.; Han, F. J.; Zhang, W. D.; Dai, Y. Y. Environ. Chem. 1998, 17, 19(in Chinese). (杨义燕, 韩扶军, 张旺德, 戴猷元, 环境化学, 1998, 17, 19.)
[24] Zhang, T.; Yuan, H.; Wang, S. Q.; Guo, X. D.; Hu, R.; Li, Y.; Yang, G. Q. RSC Adv. 2017, 7, 32861.
[25] Wang, Z.; Dai, Z.; Wu, J; Zhao, N.; Xu, J. Adv. Mater. 2013, 25, 4494.
[26] Huber, L.; Zhao, S. Y.; Malfait W. J.; Vares, S.; Koebel, M. M. Angew. Chem. Int. Ed. 2017, 56, 4753.
[27] Gao, M.; Tang, B. Z. ACS Sens. 2017, 2, 1382.
[28] Chen, M.; Sun, J. Z.; Qin A. J.; Tang, B. Z. Chin. Sci. Bull. 2016, 61, 304(in Chinese). (陈明, 孙景志, 秦安军, 唐本忠, 科学通报, 2016, 61, 304.)
[29] Mei, J.; Leung, N. L. C.; Kwok, R. T. K.; Lam, J. W. Y.; Tang, B. Z. Chem. Rev. 2015, 115, 11718.
[30] Liu, C. X.; Zou, G. R.; Peng, S.; Wang, Y. F.; Yang, W.; Wu, F.; Jiang, Z. R.; Zhang, X.; Zhou, X. Angew. Chem., Int. Ed. 2018, 57, 9689.
[31] Plata, D. L.; Briones, Y. J.; Wolfe, R. L.; Carroll, M. K.; Bakrania, S. D.; Mandel, S. G.; Anderson, A. M. J. Non-Cryst. Solids 2004, 350, 326.

快速溶剂交换法制备疏水性二氧化硅气凝胶及其负载有机荧光探针的应用研究

Preparation of Hydrophobic SiO₂ Aerogel by Rapid Solvents Exchange Method and Its Application Loaded with Organic Fluorescence Probe

PDF

Supporting Info.

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Chunyan She, Anjing Wang, Shan Liu, Wenming Shu, Weichu Yu. Preparation of Phenacyl Azides and Their Application Advances in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 481-507.
[2]	Xiao Song, Jing Qing, Jun Li, Xuelei Jia, Fusong Wu, Junrong Huang, Jian Jin, Hengzhi You. Copper-Catalyzed Asymmetric Allyl Alkylation Using Grignard Reagents under Continuous Flow [J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3174-3179.
[3]	Shutong Zhou, Shengnan Tu, Zijian Gao, Yemei Wang, Shasha Sun. Research Progress in Synthesis, Properties and Application of Subphthalocyanine [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2628-2646.
[4]	Guangli Xu, Jing Xu, Haidong Xu, Xiang Cui, Xingzhong Shu. Research Progress of Transition Metal Catalyzed Synthesis of 1,3- Conjugated Diene Compounds from Alkenes and Alkynes [J]. Chinese Journal of Organic Chemistry, 2023, 43(6): 1899-1933.
[5]	Liangru Yang, Mengli Guo, Jinwei Yuan, Jiamei Wangx, Yuting Xia, Yongmei Xiao, Pu Mao. Research Progress on Pincer N-Heterocyclic Carbene Metal Complexes [J]. Chinese Journal of Organic Chemistry, 2023, 43(6): 2002-2025.
[6]	Yangyang Li, Xiaofei Sun, Xiaoling Hu, Yuanyuan Ren, Keli Zhong, Xiaomei Yan, Lijun Tang. Synthesis of Triphenylamine Derivative and Its Recognition for Hg²⁺ with “OFF-ON” Fluorescence Response Based on Aggregation-Induced Emission (AIE) Mechanism [J]. Chinese Journal of Organic Chemistry, 2023, 43(1): 320-325.
[7]	Sihong Chen, Jiamin Xu, Yuemei Li, Baoru Peng, Lingyu Luo, Huiye Feng, Zhaohua Chen, Zhaoyang Wang. Research Progress of Aggregation-Caused Quenching (ACQ) to Aggregation-Induced Emission (AIE) Transformation Based on Organic Small Molecules [J]. Chinese Journal of Organic Chemistry, 2022, 42(6): 1651-1666.
[8]	Lixin Ju, Qi Shao, Linchuan Lu, Hongfei Lu. A New Turn-On Fluorescent Chemosensor for Selective Detection of Al³⁺ Based on a Purine Schiff Base and Its Cell Imaging [J]. Chinese Journal of Organic Chemistry, 2022, 42(6): 1706-1712.
[9]	Yuren Sun, Jiandong Liu, Quan Lin, Ken Yao, Weiqi Tong, Qun Qian. Facile Preparation of Aryl C-Glycosides by Nickel-Catalyzed Reductive Coupling of Glycosyl Halides with Aryl Halides [J]. Chinese Journal of Organic Chemistry, 2021, 41(4): 1551-1562.
[10]	Sihong Chen, Qi Chen, Shihe Luo, Xiying Cao, Guoxian Yang, Xiaoqing Zeng, Zhaoyang Wang. Progress in Design, Synthesis and Application of Triphenylamine-Based Fluorescent Probes [J]. Chinese Journal of Organic Chemistry, 2021, 41(3): 919-933.
[11]	Chaohui Cui, Yuting Liu, Ya Du. Recent Advancements of Hexaazatriphenylene-Based Materials for Energy Applications [J]. Chinese Journal of Organic Chemistry, 2021, 41(11): 4167-4179.
[12]	Han Ren, Ruxiang Li, Zhijian Chen, Lili Li, Hao Wang. Modification Methods and Applications of Self-Assembly Peptides [J]. Chinese Journal of Organic Chemistry, 2021, 41(10): 3983-3994.
[13]	Qiang Pei, Aixiang Ding, Jinjin Wu. Supramolecular Assemblies Based on Intramolecular Three-Center Hydrogen Bond and their Applications [J]. Chinese Journal of Organic Chemistry, 2021, 41(1): 105-125.
[14]	Cheng Xiaohong, Li Shuang, Wang Jingyang, Li Wangnan. “Turn-On” Fluorescent Probe for Hypochlorite: Successful Bioimaging and Real Application in Tap Water [J]. Chinese Journal of Organic Chemistry, 2020, 40(7): 1941-1947.
[15]	ChenZhang Pengfei, Lan Wenjie, Yu Xuan, Fu Bin. New Application of β,γ-Unsaturated α-Ketoesters in Asymmetric Catalysis [J]. Chinese Journal of Organic Chemistry, 2020, 40(6): 1448-1460.