Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (10): 2555-2568.DOI: 10.6023/cjoc201704011 Previous Articles     Next Articles



张凤a, 刘祥华a, 刘玮a, 邓国军b   

  1. a 湖南农业大学理学院 长沙 410128;
    b 湘潭大学化学学院 湘潭 411105
  • 收稿日期:2017-04-10 修回日期:2017-05-15 发布日期:2017-06-07
  • 通讯作者: 张凤
  • 基金资助:


Application of Pd-Monodentate Phosphorus Catalysts in the Asymmetric Hydrosilylation Reactions of Alkenes

Zhang Fenga, Liu Xianghuaa, Liu Weia, Deng Guojunb   

  1. a College of Science, Hunan Agricultural University, Changsha 410128;
    b College of Chemistry, Xiangtan University, Xiangtan 411105
  • Received:2017-04-10 Revised:2017-05-15 Published:2017-06-07
  • Contact: 10.6023/cjoc201704011
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No.21302051) and the Natural Science Foundation of Hunan Province (No.14JJ3091).

Asymmetric hydrosilylation of alkenes, which has been recognized as an important method for the preparations of optically active secondary alcohols, deserves widespread attention over the world. It is reported that such reaction can be catalyzed by Pd-monodentate phosphorus catalysts with excellent reactivity and enantioselectivity. In the past decades, a wide variety of chiral monodentate phosphorus ligands have been developed because of their stable structure, facile synthesis, convenient modification, unique efficiency. Among them, there are three predominant classes of ligands-phosphines based on an axially chiral biaryl scaffold, phosphines based on a planar chiral ferrocene scaffold and chiral phosphoramidites. Herein, the recent advances in asymmetric hydrosilylation of alkyl-substituted alkenes, styrene derivatives, 1,3-dienes and other carbon-carbon double bond compounds catalyzed by palladium monodentate phosphorus catalysts are summarized. The perspective is also discussed.

Key words: Pd catalyzed, monodentate phosphorus ligands, alkenes, asymmetric hydrosilylation