Recent Advances in Directing Group-Induced C-H Activation Reactions

doi:10.6023/cjoc201708055

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (2): 291-303.DOI: 10.6023/cjoc201708055 Previous Articles Next Articles

Special Issue: 碳氢活化合辑2018-2019

Reviews

基于导向策略的C—H键活化反应的研究进展

汪珊^a, 严沣^a, 汪连生^a, 朱磊^a,b

a 湖北工程学院化学与材料科学学院孝感 432000;
b 生物质资源转化利用湖北省协同创新中心孝感 432000

收稿日期:2017-08-26 修回日期:2017-09-21 发布日期:2017-10-24
通讯作者: 汪连生, 朱磊 E-mail:lei.zhu@hbeu.edu.cn;wangls@hbeu.edu.cn
基金资助:
国家自然科学基金（Nos.21774029，21304032）和湖北省自然科学基金（Nos.2016CFB104，2015CFC772）资助项目.

Recent Advances in Directing Group-Induced C-H Activation Reactions

Wang Shan^a, Yan Feng^a, Wang Liansheng^a, Zhu Lei^a,b

a School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000;
b Hubei Collaborative Innovation Center for Biomass Conversion and Utilization, Xiaogan 432000

Received:2017-08-26 Revised:2017-09-21 Published:2017-10-24
Contact: 10.6023/cjoc201708055 E-mail:lei.zhu@hbeu.edu.cn;wangls@hbeu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21774029, 21304032) and the Natural Science Foundation of Hubei Province (Nos. 2016CFB104, 2015CFC772).

C-H bonds are widely existed in almost all the organic compounds. Transition-metal-catalyzed C-H functionalizations usually have high reaction efficiency and high atom-economy. However, traditional strategies based on such transition-metal catalyzed C-H activations generally result in poor selectivities, because C-H bonds in one molecule facilely display similar reactivity. It is difficult to be utilized in preparation of natural products, pharmaceuticals and biomolecules. However, directing group can induce the metal to activate proximal C-H bonds via cyclometallated intermediates, improve the regioselectivity of the transformations. Therefore, it is extremely significant to deveplop auxiliary-induced C-H bonds activations. The research progress of directing group-induced C-H activation reactions and mechanisms for recent ten years are sumarized.

Key words: C-H activation, regioselectivity, directing group, transition-metal

Cite this article

Wang Shan, Yan Feng, Wang Liansheng, Zhu Lei. Recent Advances in Directing Group-Induced C-H Activation Reactions[J]. Chin. J. Org. Chem., 2018, 38(2): 291-303.

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基于导向策略的C—H键活化反应的研究进展

Recent Advances in Directing Group-Induced C-H Activation Reactions

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