α-Oxygenation of Benzylic Ethers to Esters Using MnOx-N@C Catalyst

doi:10.6023/cjoc201807011

Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (3): 811-820.DOI: 10.6023/cjoc201807011 Previous Articles Next Articles

Articles

锰氮掺杂的碳材料催化苄基醚氧化生成酯

刘晶^a, 万聪^a, 郑爱丽^a, 王连月^b, 殷凯越^a, 刘丹丹^a, 王圣德^a, 任兰会^a, 高爽^b

a 潍坊医学院药学院潍坊 261053;
b 中国科学院大连化学物理研究所大连 116023

收稿日期:2018-07-05 修回日期:2018-09-04 发布日期:2018-10-20
通讯作者: 任兰会, 高爽 E-mail:Ren_lanhui@163.com;sgao@dicp.ac.cn
基金资助:
国家自然科学基金（Nos.21773227，21773232）资助项目.

α-Oxygenation of Benzylic Ethers to Esters Using MnO_x-N@C Catalyst

Liu Jing^a, Wan Cong^a, Zheng Aili^a, Wang Lianyue^b, Yin Kaiyue^a, Liu Dandan^a, Wang Shengde^a, Ren Lanhui^a, Gao Shuang^b

a College of Pharmacy, Weifang Medical University, Weifang 261053;
b Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023

Received:2018-07-05 Revised:2018-09-04 Published:2018-10-20
Contact: 10.6023/cjoc201807011 E-mail:Ren_lanhui@163.com;sgao@dicp.ac.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21773227, 21773232).

1. α-Oxygenation of Benzylic Ethers to Esters Using MnO_x-N@C Catalyst.PDF(3949KB)

Abstract

A catalytic system for the oxidation of benzylic ethers to esters has been developed utilizing reusable MnO_x-N@C as catalyst and tert-butyl hydroperoxide (TBHP) as benign oxidant under neat condition. The catalytic oxidation system has good functional groups tolerance and excellent chemoselectivity, and this catalytic procedure can also be scaled up.

Key words: C-H bonds, oxidation, ether, ester, solvent-free

Cite this article

Liu Jing, Wan Cong, Zheng Aili, Wang Lianyue, Yin Kaiyue, Liu Dandan, Wang Shengde, Ren Lanhui, Gao Shuang. α-Oxygenation of Benzylic Ethers to Esters Using MnO_x-N@C Catalyst[J]. Chin. J. Org. Chem., 2019, 39(3): 811-820.

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锰氮掺杂的碳材料催化苄基醚氧化生成酯

α-Oxygenation of Benzylic Ethers to Esters Using MnO_x-N@C Catalyst

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