Synthesis of 10B-Enriched Borane Lewis Base Adducts

doi:10.6023/cjoc202302032

Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (5): 1772-1776.DOI: 10.6023/cjoc202302032 Previous Articles Next Articles

Special Issue: 有机硼化学专辑

ARTICLES

硼-10富集硼烷Lewis碱加合物的合成

梁沙沙^a, 马艳娜^a^,^*(), 陈学年^a^,^b^,^*()

a 郑州大学化学学院郑州 450001
b 河南师范大学化学化工学院河南新乡 453007

收稿日期:2023-02-28 修回日期:2023-04-25 发布日期:2023-04-26
通讯作者: 马艳娜, 陈学年
基金资助:
国家自然科学基金(22171246); 国家自然科学基金(22271256)

Synthesis of ¹⁰B-Enriched Borane Lewis Base Adducts

Shasha Liang^a, Yanna Ma^a(), Xuenian Chen^a^,^b()

a College of Chemistry, Zhengzhou University, Zhengzhou 450001
b School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007

Received:2023-02-28 Revised:2023-04-25 Published:2023-04-26
Contact: Yanna Ma, Xuenian Chen
Supported by:
National Natural Science Foundation of China(22171246); National Natural Science Foundation of China(22271256)

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Abstract

In nature, boron is composed of a mixture of two stable isotopes, ¹⁰B (19.78%) and ¹¹B (80.22%). The isotopical ¹⁰B-enriched compounds play important roles in many fields, such as the nuclear industry and cancer radiate treatment. Therefore, the syntheses of such kind of compounds is of important significance. These isotopical ¹⁰B-enriched compounds can be prepared from ¹⁰B-enriched boranes, however, the synthetic methods of such boranes are few. Herein, the synthetic methods of ¹⁰B-enriched Na¹⁰BH₄, THF•¹⁰BH₃, DMS•¹⁰BH₃, DMA•¹⁰BH₃, NH₃•¹⁰BH₃, Me₃N•¹⁰BH₃, Ph₃P•¹⁰BH₃, and IPr•¹⁰BH₃ were developed. Firstly, Na¹⁰BH₄ was synthesized with commercially available ¹⁰B(OH)₃ as starting material based on the modified literature methods. Then the reaction of Na¹⁰BH₄ and I₂ provided ¹⁰B₂H₆, which could rapidly react with different Lewis bases to afford corresponding L•¹⁰BH₃. Undoubtedly, these approaches provide convenient ways for the synthesis of ¹⁰B-enriched compounds.

Key words: ¹⁰B-enriched isotope, ¹⁰B(OH)₃, Na¹⁰BH₄, L•¹⁰BH₃

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Shasha Liang, Yanna Ma, Xuenian Chen. Synthesis of ¹⁰B-Enriched Borane Lewis Base Adducts[J]. Chinese Journal of Organic Chemistry, 2023, 43(5): 1772-1776.

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硼-10富集硼烷Lewis碱加合物的合成

Synthesis of ¹⁰B-Enriched Borane Lewis Base Adducts

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