Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (12): 4141-4146.DOI: 10.6023/cjoc202305003 Previous Articles     Next Articles

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手性螺旋聚合物的合成和结构控制

王倩a, 刘雨奇a, 吴宗铨b,*()   

  1. a 皖西学院材料与化工学院 安徽六安 237012
    b 吉林大学化学学院 超分子结构与材料国家重点实验室 长春 130012
  • 收稿日期:2023-05-05 修回日期:2023-06-30 发布日期:2023-08-22
  • 基金资助:
    安徽省高校自然科学研究(KJ2021A0942); 国家自然科学基金(92256201); 国家自然科学基金(22071041); 国家自然科学基金(21871073)

Synthesis and Structure Control of Chiral Helical Polymers

Qian Wanga, Yuqi Liua, Zongquan Wub,*()   

  1. a College of Materials and Chemical Engineering, West Anhui University, Lu'an, Anhui 237012
    b State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012
  • Received:2023-05-05 Revised:2023-06-30 Published:2023-08-22
  • Contact: *E-mail: zqwu@jlu.edu.cn
  • Supported by:
    Natural Science Research Project of Universities in Anhui Province(KJ2021A0942); National Natural Science Foundation of China(92256201); National Natural Science Foundation of China(22071041); National Natural Science Foundation of China(21871073)

Many researches have been done on artificial chiral helical polymers whose helical senses are excess because of their wide applications such as enantiomeric separation, photoelectric functional materials, and so on. Synthetic optically active helical polymers can be generally divided into static helical polymers and dynamic helical polymers on the basis of whether the helix inversion barriers are high or low. Among the three different kinds of helical polymers, polyisocyanates, polyisocyanides and polyacetylenes were mainly discussed in this review. And this review mainly focuses on the methods such as polymerization of chiral monomer, helix-sense-selective polymerization, chirality induction, chiral amplification, cis-cisoid to cis-transoid, polymerization-induced chiral self-assembly etc.

Key words: optically active helical polymer, polymerization of chiral monomer, helix-sense-selective polymerization, chirality induction, chiral amplification