Chin. J. Org. Chem. ›› 1987, Vol. 7 ›› Issue (1): 67-69. Previous Articles     Next Articles

5α-雄甾-16-烯-3β-对甲苯磺酸酯的溶剂解反应

韩广甸;朱莉亚   

  1. 中国医学科学院药物研究所
  • 发布日期:1987-02-25

The solvolrtic reaction of 5\a-androst-16-3\b-p-toluenesulfonate

HAN GUANGDIAN;ZHU LIYA   

  • Published:1987-02-25

Heating the title compound (I) with NaNO2 in DMF at 110?for one h gave 5a-androst-16-en-3a-ol, its formate, and 5a-androst-16-en-3-one.

Key words: PIGS, P-METHYLBENZENESULFONIC, ESTERS, ANDROSTENE, ANDROSTENE, REACTION MECHANISM, DMF, SEX PHEROMONE, ENOLS, BENZENESULFONIC ACID P, KETENE, SOLVOLYSIS

CLC Number: