The reaction of tetrafluoroethylene oligomers VIII: Intramolecular [2+2] cycloaddition of polyfluoroalkyl-allylether

Chin. J. Org. Chem. ›› 1988, Vol. 8 ›› Issue (5): 446-451. Previous Articles Next Articles

四氟乙烯齐聚体的反应 VIII: 2-(1'-烯丙氧基)四氟乙基-3-三氟甲基-3-五氧乙基全氟-1-戊烯分子内[2+2]环化加成反应

陈立佛;王均环

中国科学院上海有机化学研究所

发布日期:1988-10-25

The reaction of tetrafluoroethylene oligomers VIII: Intramolecular [2+2] cycloaddition of polyfluoroalkyl-allylether

CHEN LIFU;WANG JUNHUAN

Published:1988-10-25

Abstract

Heating CF3(C2F5)2CC(:CF2)CF(CF3)OCH2CH:CH2 at 140?for 2.5 h gave 33% intramol. adducts I and II.

Key words: INFRARED SPECTROPHOTOMETRY, MASS SPECTROGRAPHY, NMR SPECTROMETRY, CYCLIZATION, PROTON MAGNETIC RESONANCE SPECTROMETRY, CYCLOADDITION REACTION, OXYGEN HETEROCYCLICS, TETRAFLUORO ETHYLENE, PENTENE P, FLUORINE CHEMISTRY, OLIGOMER, BICYCLOHEPTANE P, PERFLUORO-HYDROCARBON, NSFC

CLC Number:

O621

Cite this article

CHEN LIFU;WANG JUNHUAN. The reaction of tetrafluoroethylene oligomers VIII: Intramolecular [2+2] cycloaddition of polyfluoroalkyl-allylether[J]. Chin. J. Org. Chem., 1988, 8(5): 446-451.

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四氟乙烯齐聚体的反应 VIII: 2-(1'-烯丙氧基)四氟乙基-3-三氟甲基-3-五氧乙基全氟-1-戊烯分子内[2+2]环化加成反应

The reaction of tetrafluoroethylene oligomers VIII: Intramolecular [2+2] cycloaddition of polyfluoroalkyl-allylether

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