Chin. J. Org. Chem. ›› 1988, Vol. 8 ›› Issue (6): 514-516. Previous Articles     Next Articles

酰基过氧化物的化学 X: 取代苯甲酰过氧化物与硝基仲烷烃的单电子氧化反应: 由硝基仲烷烃制备酮的新反应

赵成学;曲延玲;蒋锡夔   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1988-12-25

The chemistry of diacyl peroxides X: Synthesis of ketones by One-electron oxidation of carbanions derived from nitroalkanes with substituted benzoyl peroxides

ZHAO CHENGXUE;QU YANLING;JIANG XIKUI   

  • Published:1988-12-25

The carbanions derived from secondary nitroalkanes can be easily oxidized into ketones in high yields by benzoyl peroxides bearing strong electron-withdrawing substituents (p-NO2 and m-Cl) in acetonitrile at 60 癈. Thus, oxidation of anion of MePhCHNO2 with (m-ClC6H4CO2)2 gave 92% acetophenone.

Key words: NITRO COMPOUNDS, BENZENECARBOXYLIC ACID P, ALKANE P, BENZOYL GROUP, KETONE, PEROXIDE, OXIDATION REACTION

CLC Number: