Syntheses of 1,7,7-trimethylbicyclo[2.2.1]heptyl hydroxyalkyl ethers

Abstract

1,7,7-Trimethylbicyclo[2.2.1]heptyl hydroxyalkyl ethers I and II (R = H, Me; n = 1-3) were synthesized via hydroxyalkoxylations of camphene, tricyclene with C2-C4 diols in the presence of H-Mordenite, only a small amount of 6,7,7-trimethylbicyclo[2.2.1]heptyl hydroxyalkyl ethers were formed simultaneously. These reactions provided a new synthetic way for I and II with good yields.

Key words: GAS CHROMATOGRAPHY, INFRARED SPECTROPHOTOMETRY, MASS SPECTROGRAPHY, PROTON MAGNETIC RESONANCE SPECTROMETRY, MORDENITE, ETHER, PROPANEDIOL, ETHANEDIOL, BUTANEDIOL, HEPTANOL P

CLC Number:

O621

Cite this article

XIAO SHUDE;YU JINQUAN;ZHOU PING;ENG AIQUN. Syntheses of 1,7,7-trimethylbicyclo[2.2.1]heptyl hydroxyalkyl ethers[J]. Chin. J. Org. Chem., 1991, 11(3): 269-272.

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1,7,7-三甲基双环[2.2.1]庚基羟烷基醚的合成