Synthesis and crystal structure of 1, 3- bis- ( 3, 3- dimethyl- 2 -methylene indoleine) squarylium cyanine dyes

Chin. J. Org. Chem. ›› 1992, Vol. 12 ›› Issue (4): 366-372. Previous Articles Next Articles

Original Articles

1,3-二-(3,3-二甲基-2-甲烯假吲哚)方酸菁染料的合成及其晶体结构

李聚才;陈益钊;李文藻;郁陵庄

四川大学化学系

发布日期:1992-08-25

Synthesis and crystal structure of 1, 3- bis- ( 3, 3- dimethyl- 2 -methylene indoleine) squarylium cyanine dyes

LI JUCAI;CHEN YIZHAO;LI WENZAO;YU LINZHUANG

Published:1992-08-25

Abstract

Sensitizers) 2,3,3-Trimethylindolenine (I) was treated with squaric acid (II) in the presence of H2SO4 to give 1,3-bis(3,3-dimethyl-2-methyleneindolenine)squarylium cyanine dye (III). Treatment of I with 1,3-propane sultone followed by reaction with II gave 1,3-bis[N-(3-sulfonylpropyl)-3,3-dimethyl-2-methyleneindolenine]squaryli um cyanine dye. The crystal structure of III was determine by x-ray diffraction method.

Key words: CRYSTAL STRUCTURE, INDOLE P, CYANINE DYES, YLIDE, SQUARIC ACID

CLC Number:

O621

Cite this article

LI JUCAI;CHEN YIZHAO;LI WENZAO;YU LINZHUANG. Synthesis and crystal structure of 1, 3- bis- ( 3, 3- dimethyl- 2 -methylene indoleine) squarylium cyanine dyes[J]. Chin. J. Org. Chem., 1992, 12(4): 366-372.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Mengzhu Li, Boying Meng, Wenjie Lan, Bin Fu. Synthesis of 2,3-Disubstituted Dihydrobenzofurans from o-Quinone Methides and Sulfur Ylides [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 195-203.
[2]	Quanbin Jiang. Progress in Synthesis of Axially Chiral Compounds through aza-Vinylidene o-Quinone Methide Intermediates [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 159-172.
[3]	Si Wen, Yuhao Ding, Qingyu Tian, Jin Ge, Guolin Cheng. Rhodium(III)-Catalyzed Synthesis of CF₃-1H-benzo[de][1,8]naph-thyridines via C—H Activation/Annulation of Benzimidates and CF₃-Imidoyl Sulfoxonium Ylides [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 291-300.
[4]	Zuliang Chen, Yingjing Wei, Junliang Zhang. Recent Advances in Cycloaddition Reactions of Donor-Acceptor Aziridines via Carbon-Carbon Bond Cleavage [J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3078-3088.
[5]	Li Guan, Yanyan Zhou, Yongbao Mao, Kaisen Fu, Wenhui Guan, Yile Fu. Research Progress in the Synthesis of Polymethine Chain Modified Cyanine Dyes [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2682-2698.
[6]	Qifan Wang, Yuanquan Zhang, Li Xing, Yuanxiang Zhou, Chenyu Gong, Bangcan He, Nian Zhang, Yongjun Wu, Wei Xue. Design, Synthesis and Biological Activity of Myricetin Derivatives Containing 1,2,4-Triazolo[3,4-b]-1,3,4-thiadiazole [J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1525-1536.
[7]	Wenlong Chen, Huimin Li, Pengfei Yang, Dongcheng Zheng, Gaosheng Yang. Reaction of 2-Aroylmethylenemalonates with Corey Ylide [J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1472-1482.
[8]	Chunsheng Li, Xiaoqi Lian, Lianfen Chen. Copper-Catalyzed [4＋2] Annulations of Sulfoxonium Ylides and o-Phenylenediamines [J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1492-1498.
[9]	Yumei Zhong, Xiaoying Zou, Xiaoya Zhuo, Yihan Wang, Jiayi Shen, Lüyin Zheng, Wei Guo. Design, Synthesis and in vitro Anti-Cancer Activity of Novel Ethyl 4-Oxo-2-iminothiazolidin-5-ylidene Acetates [J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1452-1461.
[10]	Zhen Tang, Chao Pi, Yangjie Wu, Xiuling Cui. Rhodium-Catalyzed Tandem Acylmethylation/Annulation Reactions of 2-Aryl-2H-indazoles with Sulfoxonium Ylides: Easy Access to 6-Arylindazolo[2,3-a]quinolines [J]. Chinese Journal of Organic Chemistry, 2023, 43(3): 1187-1196.
[11]	Jing Wang, Linlin Wu, Qian Wang. Synthesis and Characterization of New Indeno[1,2-b]fluorene-6,12-dione Derivatives [J]. Chinese Journal of Organic Chemistry, 2023, 43(1): 223-228.
[12]	Jiantao Zhang, Cong Zhang, Zidong Zheng, Peng Zhou, Weibing Liu. Research Progress of Sulfoxonium Ylides in the Construction of Five/Six-Membered Nitrogen-Containing Heterocycles [J]. Chinese Journal of Organic Chemistry, 2022, 42(9): 2745-2759.
[13]	Huachao Liu, Chong Shen, Xin Chang, Chunjiang Wang. Recent Advances in Catalytic Asymmetric 1,3-Dipolar Cycloaddition Reactions with Kinetic Resolution [J]. Chinese Journal of Organic Chemistry, 2022, 42(10): 3322-3334.
[14]	Lu Wang, Ying Shao, Fan Chen, Pengcheng Qian, Jiang Cheng. Rhodium-Catalyzed Directing Group-Assisted Annulation of Arene C—H Bond with Vinylene Carbonate toward Isocoumarins [J]. Chinese Journal of Organic Chemistry, 2022, 42(1): 242-248.
[15]	Sai Shu, Zhibin Huang, Yujie Chen, Shan Yang, Yaqiqi Jiang, jingyu Zhang, Yingsheng Zhao. Rh(III)-Catalyzed [4+2] Annulation of Indoles with Sulfoxonium Ylides for the Synthesis of Dihydropyrimidoindolone Derivatives [J]. Chinese Journal of Organic Chemistry, 2021, 41(8): 3171-3179.

1,3-二-(3,3-二甲基-2-甲烯假吲哚)方酸菁染料的合成及其晶体结构

Synthesis and crystal structure of 1, 3- bis- ( 3, 3- dimethyl- 2 -methylene indoleine) squarylium cyanine dyes

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments