Chin. J. Org. Chem. ›› 1994, Vol. 14 ›› Issue (1): 94-98. Previous Articles    

Original Articles

镧系元素化合物在有机合成中的应用 ------ 酮在LnCl~3 / K 及 K 作用下的反应

王家喜;王序昆;玄镇爱   

  1. 南开大学元素有机化学研究所
  • 发布日期:1994-02-25

Applition of lanthanide compounds in organic synthesies ------ reaction of ketones in presence of LnCl~3 / K or K

WANG JIAXI;WANG XUKUN;XUAN ZHENAI   

  • Published:1994-02-25

In the presence of LnCl~3 / K (Ln = Nd, Gd) or K aromatic ketones undergo reductive dimerization, whereas aliphatic ketones give aldol condensation. The possible mechanisms is suggested.

Key words: LANTHANIDE SERIES COMPOUNDS, KETONE

CLC Number: