Chin. J. Org. Chem. ›› 1994, Vol. 14 ›› Issue (4): 414-416. Previous Articles     Next Articles

Original Articles

在钾 / 乙二胺中的室温光诱导S~R~N1反应

吴国生;曾繁文;陶涛;王冬梅   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1994-08-25

Photo-S~R~N1 reaction in K / (NH~2CH~2)~2 at room temperature

WU GUOSHENG;ZENG FANWEN;TAO TAO;WANG DONGMEI   

  • Published:1994-08-25

Photo-S~R~N1 reactions of chloronaphthalene, 4-bromobiphenyl with carbanions derived from t-butyl acetate, morphine propionate, acetonitrile and propionitrile, operated in K / (NH~2CH~2)~2 at room temperature . In comparison with the Photo-S~R~N1 in K / NH~3, the yield of ArNu decreased to moderate level (ca. 50%) while the amount of ArH increased dramatically (yield, 20-40%).

Key words: CARBANION, POTASSIUM

CLC Number: