Studies on synthesis of butyl acetate with  solid-supported rare- earth metal sulphate as catalyst

Abstract

This paper reports studies on synthesis of butyl acetate with solid- supported rare-earthmetal sulphate as catalyst. The solid-supported catalysts are man-made zeolite, active carbon and cation-exchange resin. The best catalyst for synthesis of butyl acetate is found to be the cation-exchange resin supported rare-earth metal sulphate. The yield is 97.2%. The properties of the catalyst is also discussed.

Key words: SUPERACID, SUPPORTED CATALYST, ESTERIFICATION, ESSENCES, BUTYL ACETATE, RARE EARTH CATALYST, SOLID ACID CATALYST

CLC Number:

O621
TQ65

Cite this article

Lu Zekai;Zhu Wanren. Studies on synthesis of butyl acetate with solid-supported rare- earth metal sulphate as catalyst[J]. Chin. J. Org. Chem., 2000, 20(5): 819-821.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Yunzhe Zhong, Ying hen, Lei Yu, Hongwei Zhou. Electrochemical Mediated Esterification Reaction of Carboxylic Acids and Alcohols [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2855-2863.
[2]	Yijun Shi, Xinyue Sun, Han Cao, Fusheng Bie, Jie Ma, Zhe Liu, Xingshun Cong. Thioesterification of Esters with Primary Aliphatic Thiols at Room Temperature [J]. Chinese Journal of Organic Chemistry, 2023, 43(7): 2499-2505.
[3]	Zehui Li, Haoyu Zou, Lincai Li, Yiling Zhao, Hongping Zhu. Synthesis and Propylene Oxide Carbonylation Hydroesterification Catalytic Property of N,O-Ligand Coordination Cobalt Compounds [J]. Chinese Journal of Organic Chemistry, 2023, 43(11): 3907-3915.
[4]	Jiahao Li, Hongqiang Liu, Bo Zhang, Bingyang Ge, Dawei Wang. Synthesis of Supported Indazolyl-Pyridyl-Quinoline Iridium Catalyst and Its Application to N-Alkylation of 2-Aminobenzothiazoles [J]. Chinese Journal of Organic Chemistry, 2022, 42(2): 619-630.
[5]	Peng Wang, Da Yang, Huan Liu. Recent Advances on Carbonylation of 1,3-Dienes [J]. Chinese Journal of Organic Chemistry, 2021, 41(9): 3379-3389.
[6]	Shiyan Cheng, Chuhong Ou, Hongmin Lin, Junsong Jia, Haitao Tang, Yingming Pan, Guobao Huang, Xiujin Meng. Electrochemically Mediated Esterification of Aromatic Aldehydes with Aliphatic Alcohols via Anodic Oxidation [J]. Chinese Journal of Organic Chemistry, 2021, 41(12): 4718-4724.
[7]	Yu Jieqiang, Jia Jun, Wang Xingwang. Synthesis of a Type of Linear β,γ-Unsaturated α-Keto Tryptophol Ester Compounds [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2778-2787.
[8]	Ma Hongpeng, Bai Chaolumen, Bao Yongsheng. Nano-Gold Catalyzed Transesterification of (Hetero) aryl Esters with Alkyl Halides via C-O Activation [J]. Chin. J. Org. Chem., 2019, 39(3): 734-746.
[9]	Menggen qiqige, Wu Yun, Bao Yongsheng. Metal-Free Esterification of Aldehydes or Carboxylic Acids with Quaternary Ammonium Salts [J]. Chin. J. Org. Chem., 2018, 38(4): 902-911.
[10]	Ding Haixin, Li Chuang, Dong Xiangyou, Cao Banpen, Zhang Ning, Hong Sanguo, Xiao Qiang. First Total Synthesis of Marine Natural Nucleoside Kipukasin D [J]. Chin. J. Org. Chem., 2018, 38(12): 3351-3355.
[11]	Ju Lei, Ma Chunmei, Tang Mi, Wang Yanhui, Yu Xinhong, Ma Hongmei. N-Heterocyclic Carbene-Catalyzed Oxidative Esterification of Aldehydes: Facile Access to α-Acyloxyacetates and Cyanomethyl Esters [J]. Chin. J. Org. Chem., 2018, 38(11): 3056-3062.
[12]	Li Xiaowei, Zhou Jin, Zhuo Shuping. Recent Progress of Supported N-Heterocyclic Carbene Catalyst in Organic Reactions [J]. Chin. J. Org. Chem., 2016, 36(7): 1484-1500.
[13]	Xiao Jianjun, Qiu Zumin, He Weijuan, Du Chengcheng, Zhou Wei. Progress in Platinum Catalysts Supported by Inorganic Carriers for Hydrosilylation [J]. Chin. J. Org. Chem., 2016, 36(5): 987-999.
[14]	Zhang Haifei, Liu Dongmei, Kang Tingting, Wang Ye, Zhang Xiaoxiang, Zhu Xinbao. Synthesis of Novel Benzothiazolium Ionic Liquids and Research on Their Catalytic Esterification for Ricinoleic Acid [J]. Chin. J. Org. Chem., 2016, 36(5): 1104-1110.
[15]	Hu Jingjing, Zhao Dishun, Li Jingjing, Zhai Jianhua, Hu Tiantian. Synthesis and Catalytic Esterification Performance of Caprolactam Task-Specific Ionic Liquids [J]. Chin. J. Org. Chem., 2015, 35(8): 1773-1780.

固载超强酸催化剂制备及催化合成乙酸正丁酯的研究

Studies on synthesis of butyl acetate with solid-supported rare- earth metal sulphate as catalyst

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments