Synthesis and characterization of (E)-cinnamoylferrocene- dithioylcarbohydrazones  and their Cu(Ⅱ) and Zn(Ⅱ)complexes

Abstract

Two Schiff base of HCFM [(E)-cinnamoylferrocene-(S)- methyldithioylcarbohydrazone] and HCFB [(E)-cinnamoylferrocene- (S)- Benzyldithioylcarbohydrazone] as well as six complexes of these schiff bases. Cu(CFM)2 · H2O, Cu(CFM)OAc· H2O, Cu (CFB)2·H2O, Zn(CFM)2· 2H2O, Zn(CFM)OAc· H2O and Zn(CFB)2, have been synthesized and characterized. The possible coordinating progess and complex structures are discussed. It is found that the ligands are bidentate with trans configuation coordinating to the metal ions via nitrogen and sulfer atoms after their tautomerizaation of thione to thiol and deprotonation of the thiol.

Key words: HYDRAZINO, CARBOHYDRAZIDE P, MULTIDENTATE LIGANDS, DITHIOZONE, HYDRAZONEETHYL, FERROCENE P, COPPER COMPLEX, ZINC COMPLEX, SCHIFF BASE, STRUCTURE CHARACTERISTICS

CLC Number:

O627

Cite this article

Liu Yonghong;Liu Xiaolan;Yang Sheng;Ma Yongxiang. Synthesis and characterization of (E)-cinnamoylferrocene- dithioylcarbohydrazones and their Cu(Ⅱ) and Zn(Ⅱ)complexes[J]. Chin. J. Org. Chem., 2001, 21(3): 218-222.

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