Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (1): 7-14. Previous Articles     Next Articles

烯烃的有机催化不对称环氧化研究进展及催化剂设计

张治国, 王歆燕, 孙川, 石鸿昌*   

  1. 清华大学化学系 北京 100084
  • 收稿日期:2003-01-23 修回日期:2003-03-24 接受日期:2003-05-30 发布日期:2022-09-21
  • 基金资助:
    清华大学985药学基金资助项目.

Organocatalytic Asymmetric Epoxidation of Olefins and Design of Chiral Catalysts

ZHANG Zhi-Guo, WANG Xin-Yan, SUN Chuan, SHI Hong-Chang*   

  1. Department of Chemistry, Tsinghua University, Beijing 100084
  • Received:2003-01-23 Revised:2003-03-24 Accepted:2003-05-30 Published:2022-09-21
  • Contact: *E-mail: shihc@mail.tsinghua.edu.cn; Fax: 010-62771149

Organocatalytic asymmetric epoxidation of olefins by oxaziridine, chiral iminium salt, chiral ketone and chiral amine was reviewed. Moreover, the strategy for the design of the chiral catalysts according to the catalytic mechanisms was discussed.

Key words: asymmetric epoxidation, organic catalysis, oxygen transfer, oxaziridine, oxaziridium salt amine