Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (9): 2607-2625.DOI: 10.6023/cjoc202004042 Previous Articles     Next Articles


袁康宁a, 赵玉英b, 常宏宏a, 田俊a, 高文超a   

  1. a 太原理工大学生物医学工程学院 太原 030024;
    b 太原科技大学化学与生物工程学院 太原 030021
  • 收稿日期:2020-04-26 修回日期:2020-05-16 发布日期:2020-06-01
  • 通讯作者: 高文超
  • 基金资助:

Recent Advances in AlCl3-Promoted Organic Reactions

Yuan Kangninga, Zhao Yuyingb, Chang Honghonga, Tian Juna, Gao Wenchaoa   

  1. a College of Biomedical Engineering, Taiyuan University of Technology, Taiyuan 030024;
    b School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030021
  • Received:2020-04-26 Revised:2020-05-16 Published:2020-06-01
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 21901179), the Key Research and Development Program of Shanxi Province (International Cooperation) (No. 201803D421093), the Natural Science Foundation of Shanxi Province (No. 201901D211052) and the Research Project Supported by Shanxi Scholarship Council of China (Nos. HGKY2019029, 2020-053).

As a representative hard Lewis acid, aluminum trichloride (AlCl3) has attracted more and more attention in the past decades. The reactions promoted via the activation of halogens, oxygen, nitrogen, sulfur compounds and π-bonds with AlCl3 are systematically reviewed, and some recent progress in last ten years is updated as well. Moreover, the new application fields of AlCl3 are prospected.

Key words: aluminum trichloride, activation, activation mechanism, organic catalysis