Synthesis and Characterization of Caged Bicyclic Phosphorous Quadridentate Silicon Complex

Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (08): 1125-1129. Previous Articles Next Articles

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双环笼状四配位硅的合成及其结构表征

张利利，刘安华*，曾幸荣，温永向

(华南理工大学材料科学与工程学院广州 510640)

收稿日期:2005-10-24 修回日期:2006-02-23 发布日期:2006-07-26
通讯作者: 刘安华

Synthesis and Characterization of Caged Bicyclic Phosphorous Quadridentate Silicon Complex

ZHANG Li-Li,LIU An-Hua*,ZENG Xing-Rong,WEN Yong-Xiang

(College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640)

Received:2005-10-24 Revised:2006-02-23 Published:2006-07-26
Contact: LIU An-Hua

Abstract

A novel caged bicyclic phosphorous quadridentate silicon complex was synthesized by reaction of 1-oxo-1-phospha-4-chloromethyl-2,6,7-trioxabicyclo[2.2.2]octane with the pentacoordinate silicon complex, which was synthesized directly from SiO₂by non-carbothermal reduction. Structure of the synthesized substance was confirmed by FTIR, MS,¹³C and ²⁹Si MAS NMR spectra, while thermal analysis tests indicated that the target compound possessed exceptional thermal stability.

Key words: caged bicyclic phosphorous quadridentate silicon complex, silica, synthesis, charaterization

Cite this article

ZHANG Li-Li,LIU An-Hua*,ZENG Xing-Rong,WEN Yong-Xiang. Synthesis and Characterization of Caged Bicyclic Phosphorous Quadridentate Silicon Complex[J]. Chin. J. Org. Chem., 2006, 26(08): 1125-1129.

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双环笼状四配位硅的合成及其结构表征

Synthesis and Characterization of Caged Bicyclic Phosphorous Quadridentate Silicon Complex

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