Studies on the Electrosynthesis of Pinacols

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Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (08): 1130-1132. Previous Articles Next Articles

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片呐醇电合成的研究

边延江*^,1，杨卫民¹，李记太²

(¹廊坊师范学院化学系廊坊 065000)
(²河北大学化学系保定 071002)

收稿日期:2005-08-04 修回日期:2006-02-28 发布日期:2006-07-26
通讯作者: 边延江

Studies on the Electrosynthesis of Pinacols

BIAN Yan-Jiang*^,1,YANG Wei-Min¹,LI Ji-Tai²

(¹Department of Chemistry, Langfang Normal College, Langfang 065000)
(²Department of Chemistry, Hebei University, Baoding 071002)

Received:2005-08-04 Revised:2006-02-28 Published:2006-07-26

Contact: BIAN Yan-Jiang

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Abstract

Electrosynthesis of pinacols by aluminum alloy as electrode in acid condition was performed, with the influence of electric potential and time on pinacol yield explored. The optimal reaction conditions were electric potential 12 V, time 60～80 min, methanol 5 mL, hydrochloric acid (36%) 5 mL, with the yields of pinacols up to 31%～81%.

Key words: aluminum alloy electrode, pinacol, electrosynthesis

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BIAN Yan-Jiang*^,1,YANG Wei-Min,LI Ji-Tai². Studies on the Electrosynthesis of Pinacols[J]. Chin. J. Org. Chem., 2006, 26(08): 1130-1132.

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[1]	Zhicheng Bao, Muyao Li, Jianbo Wang. Copper-Catalyzed Cross-Coupling of Aryldiazoacetates with Bis[(pinacolato)boryl]methane [J]. Chinese Journal of Organic Chemistry, 2023, 43(5): 1808-1814.
[2]	Jiantao Zhang, Yawen Deng, Nuolin Mo, Lianfen Chen. Advances in Radical Mediated 1,2-Aryl Migration Reactions of α,α-Diarylallyl Alcohols [J]. Chinese Journal of Organic Chemistry, 2023, 43(2): 426-435.
[3]	Zhaoxin Wei, Renjie Wang, Yonghong Zhang, Bin Wang, Yu Xia, Weiwei Jin, Chenjiang Liu. Electrochemical Synthesis of N-Acyl/Sulfonylsulfenamides Using Potassium Iodide as Mediator [J]. Chinese Journal of Organic Chemistry, 2022, 42(11): 3730-3739.
[4]	Wei Meng, Kun Xu, Bingbing Guo, Chengchu Zeng. Recent Advances in Minisci Reactions under Electrochemical Conditions [J]. Chinese Journal of Organic Chemistry, 2021, 41(7): 2621-2635.
[5]	Linlin Li, Xiaoyu Chen, Congcong Pei, Jingya Li, Dapeng Zou, Yangjie Wu, Yusheng Wu. Transition Metal-Free Deuteride Reduction of N-tert-Butanesulfinyl Ketimines Derivatives via B₂pin₂/D₂O System [J]. Chinese Journal of Organic Chemistry, 2021, 41(6): 2319-2325.
[6]	Muxue He, Shiyan Cheng, Yongzhou Pan, Haitao Tang, Yingming Pan. Electrochemically Mediated S—N Bond Formation: Synthesis of Sulfenamides [J]. Chinese Journal of Organic Chemistry, 2021, 41(6): 2354-2360.
[7]	Shiyan Cheng, Chuhong Ou, Hongmin Lin, Junsong Jia, Haitao Tang, Yingming Pan, Guobao Huang, Xiujin Meng. Electrochemically Mediated Esterification of Aromatic Aldehydes with Aliphatic Alcohols via Anodic Oxidation [J]. Chinese Journal of Organic Chemistry, 2021, 41(12): 4718-4724.
[8]	Hehua Xu, Xiangtai Meng, Yu Zheng, Jinyue Luo, Shenlin Huang. Electrochemical Annulations of o-Alkynylanilines for Synthesis of 3-Iodoindoles [J]. Chinese Journal of Organic Chemistry, 2021, 41(12): 4696-4703.
[9]	Pan Chao, Liu Peng, Wu An'guo, Li Ming, Wen Lirong, Guo Weisi. Electrochemical-Promoted Synthesis of 2-Thiazolines via Selenylation/Cyclization of N-Allylthioamides [J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2855-2862.
[10]	Li Mengfan, Wang Rong, Hao Wenjuan, Jiang Bo. Electrocatalytic Synthesis of 2,5-Disubstituted 1,3,4-Oxadiazoles [J]. Chinese Journal of Organic Chemistry, 2020, 40(6): 1540-1548.
[11]	Hu Yongqin, Huang Danfeng, Wang Kehu, Zhao Zhuanxia, Zhao Fangxia, Xu Weigang, Hu Yulai. Study on Allylation Reactions of Trifluoromethylated Acylhydrazones with Allylsilanes or Allylboronates [J]. Chinese Journal of Organic Chemistry, 2020, 40(6): 1689-1696.
[12]	Liu Wenbo, Lu Zhan. Application of Pinacolborane in Catalytic Enantioselective Hydroboration of Ketones and Imines [J]. Chinese Journal of Organic Chemistry, 2020, 40(11): 3596-3604.
[13]	Liu Xueying, Liu Zhenwei, Guo Yuanyuan, Li Jingya, Zou Dapeng, Wu Yusheng, Wu Yangjie. One-Pot, Two-Step Reductive Amination of Boronate Ester Containing Aromatic Amines and Aldehydes Using B₂pin₂ as Reductant [J]. Chin. J. Org. Chem., 2019, 39(7): 2001-2008.
[14]	Feng Enqi, Hou Zhongwei, Xu Haichao. Electrochemical Synthesis of Tetrasubstituted Hydrazines by Dehydrogenative N-N Bond Formation [J]. Chin. J. Org. Chem., 2019, 39(5): 1424-1428.
[15]	BIAN Yan-Jiang, ZHANG Gao-Feng. Reductive Coupling Reactions of Aromatic Aldehydes Using Zinc as Electrode in Aqueous Media [J]. Chin. J. Org. Chem., 2010, 30(08): 1237-1239.