Synthesis and Crystal Structure of 3-Methoxyl-5-chloro-2,6-dinitropyridine

Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (01): 123-126. Previous Articles Next Articles

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3-甲氧基-5-氯-2,6-二硝基吡啶的合成及晶体结构

陈军，李全良，王建龙*，耿天奇

(^a中北大学化工与环境学院太原 030051)

收稿日期:2006-11-01 修回日期:1900-01-01 发布日期:2008-01-23
通讯作者: 王建龙

Synthesis and Crystal Structure of 3-Methoxyl-5-chloro-2,6-dinitropyridine

CHEN Jun, LI Quan-Liang, WANG Jian-Long*, GENG Tian-Qi

(^aSchool of Chemical Engineering and Environment, North University of China, Taiyuan 030051)

Received:2006-11-01 Revised:1900-01-01 Published:2008-01-23
Contact: WANG Jian-Long

Abstract

3-Methoxyl-5-chloro-2,6-dinitropyridine was synthesized from 3,5-dichloropyridine by substitution and nitration, and characterized by single crystal X-ray diffraction analysis, IR, ¹H NMR, MS spectra and elemental analysis. The crystal is in monoclinic system with space group P2₁/n, and the unit cell parameters as follows: a＝0.66490(13) nm, b＝1.0842(2) nm, c＝1.2715(3) nm, β＝95.55(3)°, V＝0.9123(3) nm³; Z＝4, D_c＝1.701 g•cm^－3; F(000)＝472; μ＝0.426 mm^－1.

Key words: 3-methoxyl-5-chloro-2,6-dinitropyridine, 3,5-dichloropyridine, crystal structure

Cite this article

CHEN Jun, LI Quan-Liang, WANG Jian-Long*, GENG Tian-Qi. Synthesis and Crystal Structure of 3-Methoxyl-5-chloro-2,6-dinitropyridine[J]. Chin. J. Org. Chem., 2008, 28(01): 123-126.

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3-甲氧基-5-氯-2,6-二硝基吡啶的合成及晶体结构

Synthesis and Crystal Structure of 3-Methoxyl-5-chloro-2,6-dinitropyridine

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