Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (06): 948-955. Previous Articles     Next Articles

Original Articles

顶空-气相色谱-质谱联用分析桂花和叶中挥发性成分

王呈仲a,b; 苏 越*,a ; 郭寅龙*,b   

  1. (a上海中医药大学中医复杂系统研究中心 上海 201203)
    (b中国科学院上海有机化学研究所上海质谱中心 上海 200032)
  • 收稿日期:2008-12-04 修回日期:2009-02-12 发布日期:2009-06-20
  • 通讯作者: 苏 越*,a ; 郭寅龙*,b

Analysis of the Volatile Components from Flowers and Leaves of Osmanthus fragrans Lour. by Headspace-GC-MS

Wang, Chengzhong a,b; Su, Yue*,a; Guo, Yinlong*,b   

  1. (a Research Center for Traditional Chinese Medicine Complexity System, Shanghai University of Traditional
    Chinese Medicine, Shanghai 201203)
    (b Shanghai Mass Spectrometry Center, Shanghai Institute of Organic Chemistry,
    Chinese Academy of Sciences, Shanghai 200032)
  • Received:2008-12-04 Revised:2009-02-12 Published:2009-06-20
  • Contact: Su, Yue*,a; Guo, Yinlong*,b

A multidimensional qualitative analysis approach, consisting of accurate mass measurement, retention index, MS/MS and mass spectrum search, has been proposed to identify compounds, which could improve efficiency and accuracy of qualitative analysis. Headspace-gas chromatography-quadrupole mass spectrometry, headspace-gas chromatography-time of flight mass spectrometry and headspace-gas chroma-tography-tandem mass spectrometry have been utilized to analyze volatile components from Osmanthus fragrans Lour., which were identified by the above multidimensional qualitative analysis approach. The re-sults showed that 47 volatile compounds were totally identified, of which monoterpene and sesquiterpene compounds were the main components. This qualitative analysis strategy is accurate and reliable, and can be widely applied to qualitative analysis of the volatile components from complex samples.

Key words: volatile compone, accurate mass measurement, Osmanthus fra-grans Lour., retention index, MS/MS, mass spectrum search