Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (04): 595-600. Previous Articles     Next Articles

Notes

氮-二供电子链取代邻苯二甲酰亚胺衍生物的光诱导单电子转移环化反应

金英学*,1,谭广慧1,王天赤1,魏树权1,王进军2   

  1. (1哈尔滨师范大学化学化工学院 哈尔滨 150025)
    (2烟台大学化学生物理工学院 烟台 264005)
  • 收稿日期:2009-05-27 修回日期:2009-08-10 发布日期:2010-04-28
  • 通讯作者: 金英学 E-mail:yenghak@hrbnu.edu.cn

Photoinduced Cyclization Reactions of Phthalimide Derivatives N-Linked Two Electrondonating Chains by Single Electron Transfer

Jin Yingxue*,1 Tan Guanghui1 Wang Tianchi1 Wei Shuquan1 Wang Jinjun2   

  1. (1 College of Chemistry & Chemical Engineering, Harbin Normal University, Harbin 150025)
    (2 Science and Engineering College of Chemistry and Biology, Yantai University, Yantai 264005)
  • Received:2009-05-27 Revised:2009-08-10 Published:2010-04-28

Phthalimide derivatives containing a shorter thioether chain and a longer poly-ethylenoxy chain could undergo a photoinduced single electron transfer cyclization reaction in methanol solvent to provide cylic compounds that were constituted with the shorter thioether chain in high regioselectivity and high yield. The structures of all new compounds were confirmed by NMR and EI-MS data.

Key words: electrondonating bis-chain, phthalimide, single electron transfer, cyclization reaction