A Colorimetric/Fluorescent Chemosensor for Dysprosium(III) Ion: Design and Synthesis of a Calix[4]arene-Schiff Base

Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (11): 1672-1676. Previous Articles Next Articles

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镝(III)离子比色/荧光传感器: 杯芳席夫碱的设计与合成

刘志莲*^{,1,2，张书香¹，王志玲¹，夏光明¹，高云华²}

(¹济南大学化学化工学院山东省氟化学化工材料重点实验室济南 250022)
(²中国科学院理化技术研究所中国科学院光化学转换与功能材料重点实验室北京 100190)

收稿日期:2009-12-18 修回日期:2010-06-01 发布日期:2010-06-07
通讯作者: 刘志莲 E-mail:zhilianliu@163.com
基金资助:
金属离子识别型光调控分子器件的设计及其应用的研究;类蝶状结构逆转录酶抑制剂的合成及抗病毒性能;分子/离子识别型光调控分子器件的基础研究

A Colorimetric/Fluorescent Chemosensor for Dysprosium(III) Ion: Design and Synthesis of a Calix[4]arene-Schiff Base

Liu Zhilian*^{,1,2 Zhang Shuxiang¹ Wang Zhil-ing¹ Xia Guangming¹ Gao Yunhua²}

(¹ Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022)
(² Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemis-try, Chinese Academy of Sciences, Beijing 100190)

Received:2009-12-18 Revised:2010-06-01 Published:2010-06-07

Abstract

A novel photochromic Schiff base derivatives carrying a calix[4]arene group have been synthesized through incorporating two imine groups into the upper rim of a calix[4]arene. The addition of dysprosium(III) ion (Dy^3＋) to the Schiff base compound resulted in the solution color change from colorless to yellow. No color change was observed in the solution of model compoud without calix[4]arene cavity upon addition of Dy^3＋. It indicates that the synthetic receptor can effectively recognize Dy^3＋ion by naked eyes over other cations. The chemosensor can be applied in analytical chemistry for detection of Dy^3＋ions.

Key words: colorimetric/fluorescent chemosensor, calix[4]arene, Schiff base, Dy^3＋

Cite this article

LIU Zhi-Lian, ZHANG Shu-Xiang, WANG Zhi-Ling, XIA Guang-Ming, GAO Yun-Hua. A Colorimetric/Fluorescent Chemosensor for Dysprosium(III) Ion: Design and Synthesis of a Calix[4]arene-Schiff Base[J]. Chin. J. Org. Chem., 2010, 30(11): 1672-1676.

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镝(III)离子比色/荧光传感器: 杯芳席夫碱的设计与合成

A Colorimetric/Fluorescent Chemosensor for Dysprosium(III) Ion: Design and Synthesis of a Calix[4]arene-Schiff Base

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