Pd/C-Catalyzed Transfer Hydrogenation with Hantzsch Ester 1,4-Dihydropyridine for the Reduction of Aromatic Azides,  Aromatic Nitro Compounds and Olefins

Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (02): 229-233. Previous Articles Next Articles

Original Articles

Pd/C催化下汉斯酯1,4-二氢吡啶还原芳香叠氮化合物、芳香硝基化合物以及碳碳双键的反应研究

牛秀琴 ; 刘振刚 ; 于炜*; 吴隆民

(兰州大学功能有机分子化学国家重点实验室兰州 730000)

收稿日期:2008-06-04 修回日期:2008-08-13 发布日期:2009-02-20
通讯作者: 于炜

Pd/C-Catalyzed Transfer Hydrogenation with Hantzsch Ester 1,4-Dihydropyridine for the Reduction of Aromatic Azides, Aromatic Nitro Compounds and Olefins

Niu, Xiuqin; Liu, Zhengang; Yu, Wei* ; Wu, Longmin

(State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000)

Received:2008-06-04 Revised:2008-08-13 Published:2009-02-20
Contact: Yu, Wei

Abstract

The Pd/C-catalyzed transfer hydrogenation with Hantzsch ester 1,4-dihydropyridine (HEH) provides an efficient protocol for the selective reduction of aromatic azides to the corresponding amines. The method is advantageous in terms of high yield and high selectivity. The reduction of aromatic nitro compounds can also be achieved with the method. In addition, the reagent combination of HEH-Pd/C is also effective for the reduction of conjugated olefins.

Key words: aromatic azide, Hantzsch ester 1,4-dihydropyridine, aromatic nitro compound, reduction, Pd/C

Cite this article

Niu, Xiuqin; Liu, Zhengang; Yu, Wei* ; Wu, Longmin. Pd/C-Catalyzed Transfer Hydrogenation with Hantzsch Ester 1,4-Dihydropyridine for the Reduction of Aromatic Azides, Aromatic Nitro Compounds and Olefins[J]. Chin. J. Org. Chem., 2009, 29(02): 229-233.

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Pd/C催化下汉斯酯1,4-二氢吡啶还原芳香叠氮化合物、芳香硝基化合物以及碳碳双键的反应研究

Pd/C-Catalyzed Transfer Hydrogenation with Hantzsch Ester 1,4-Dihydropyridine for the Reduction of Aromatic Azides, Aromatic Nitro Compounds and Olefins

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Pd/C催化下汉斯酯1,4-二氢吡啶还原芳香叠氮化合物、芳香硝基 化合物以及碳碳双键的反应研究

Pd/C-Catalyzed Transfer Hydrogenation with Hantzsch Ester 1,4-Dihydropyridine for the Reduction of Aromatic Azides, Aromatic Nitro Compounds and Olefins

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

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Metrics

Comments

Pd/C催化下汉斯酯1,4-二氢吡啶还原芳香叠氮化合物、芳香硝基化合物以及碳碳双键的反应研究