Solid-liquid phase transfer catalytic synthesis IV. \a\-methyl serine and other amino acids

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Chin. J. Org. Chem. ›› 1987, Vol. 7 ›› Issue (5): 357-361. Previous Articles Next Articles

固-液相转移催化合成IV.α-甲基丝氨酸及其它氨基酸

邬胜德;刘桂兰;陈代谟;蒋耀忠

中国科学院成都有机化学研究所

发布日期:1987-10-25

Solid-liquid phase transfer catalytic synthesis IV. \a\-methyl serine and other amino acids

WU SHENGDE;LIU GUILAN;CHEN DAIMO;JIANG YAOZHONG

Published:1987-10-25

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Abstract

Seven amino acids, including serine and a-methylserine, were synthesized under mild solid-liq. phase transfer catalytic conditions via alkylation of the Schiff base produced from reaction of glycine Et ester or alanine Me ester with benzaldehyde.

Key words: AMINO ACID, HYDROLYSIS, ALKYLATION, PHASE TRANSFER CATALYSIS, AMMONIUM CHLORIDE, BENZALDEHYDE, SCHIFF BASE, GLYCINE, SERINE

CLC Number:

O621
O643

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WU SHENGDE;LIU GUILAN;CHEN DAIMO;JIANG YAOZHONG. Solid-liquid phase transfer catalytic synthesis IV. \a\-methyl serine and other amino acids[J]. Chin. J. Org. Chem., 1987, 7(5): 357-361.

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固-液相转移催化合成IV.α-甲基丝氨酸及其它氨基酸

Solid-liquid phase transfer catalytic synthesis IV. \a\-methyl serine and other amino acids

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