Chin. J. Org. Chem. ›› 1983, Vol. 3 ›› Issue (4): 257-262. Previous Articles     Next Articles

有机反应立体选择性的量子化学研究

陈念陔;周碧荷   

  1. 黑龙江大学化学系
  • 发布日期:1983-08-25

Study on stereoselectivity of organic reactions by quantum chemistry

CHEN NIANGAI;ZHOU BIHE   

  • Published:1983-08-25

This paper discusses the stereoselection in organic chemistry from the point of view of the MO theory, and uses the HMO method with \s\-π interaction, considering the effect of electron density, to explain the stereoselectivity of addition reaction, elimination reaction and SN2' reaction. The theoretical predictions agree closely with the experimental results.

Key words: SUBSTITUTION REACTION, QUANTUM CHEMISTRY, ELIMINATION REACTION, STEREOSELECTIVITY, MOLECULAR ORBITAL THEORY, NUCLEOPHILIC REACTION, ADDITION REACTION, HUCKEL MOLECULAR ORBITAL

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