Studies on organosilicon compounds with biological activity VIII. Study of 1-arylacyloxy-2,8,9-trioxa-5-aza-1-silatricyclo [3.3.3.0[1.5]] undecanes

Abstract

Nine 1-arylacyloxy-2,8,9-trioxa-5-aza-1-silatricyclo[3.3.3.01,5]undecanes were synthesized by reaction between 1-bromosilatrane and substituted benzoic acids. The crystal structure of I was studied by X-ray diffraction, confirming the 5-coordinated structures of these compounds The intramol. N甋i bond was stronger than that of ordinary silatranes. The 1H NMR and IR of these compounds were studied and the mass spectral fragmentation paths was rationalized.

Key words: X-RAY DIFFRACTION ANALYSIS, MASS SPECTROGRAPHY, NITROGEN HETEROCYCLICS, PROTON MAGNETIC RESONANCE SPECTROMETRY, C11 COMPOUNDS, SILICON HETEROCYCLICS COMPOUNDS, TRICYCLIC HYDROCARBON P, OXYGEN HETEROCYCLICS, ORGANO SILICON COMPOUNDS, BIOLOGICAL ACTIVITY

CLC Number:

O627

Cite this article

WANG JITAO;XIE QINGLAN;LIAO RENAN;LI JING;LIN XIUYUN. Studies on organosilicon compounds with biological activity VIII. Study of 1-arylacyloxy-2,8,9-trioxa-5-aza-1-silatricyclo [3.3.3.0[1.5]] undecanes[J]. Chin. J. Org. Chem., 1987, 7(4): 285-288.

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具有生物活性的有机硅化合物的研究VII.1-芳酰氧基-2,8,9-三氧杂-5-氮杂-1-硅杂三环[3,3,3,0[1.5]]十一碳烷的研究