Synthesis and Structural Characterization of Triphenyltin N-(5-Chlorosalicylidene)-α-amino Carboxylates

Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (10): 1258-1263. Previous Articles Next Articles

Original Articles

三苯基锡N-(5-氯亚水杨基)-α-氨基酸酯的合成及结构表征

田来进*^,a，刘西成^a，毛武涛^a，孙玉希^a，刘希杰^b，周正宇^a,c

(^a曲阜师范大学化学系曲阜273165)
(^b中国科学院化学研究所北京100080)
(^c山东大学晶体材料国家重点实验室济南 250100)

收稿日期:2006-10-19 修回日期:2006-12-25 发布日期:2007-09-28
通讯作者: 田来进

Synthesis and Structural Characterization of Triphenyltin N-(5-Chlorosalicylidene)-α-amino Carboxylates

TIAN Lai-Jin*^,a,LIU Xi-Cheng^a,MAO Wu-Tao^a
SUN Yu-Xi^a,LIU Xi-Jie^b,ZHOU Zheng-Yu^a,c

(^a Department of Chemistry, Qufu Normal University, Qufu 273165)
(^b Institute of Chemistry, Chinese Academy of Science, Beijing 100080)
(^c State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100)

Received:2006-10-19 Revised:2006-12-25 Published:2007-09-28
Contact: TIAN Lai-Jin

Abstract

Triphenyltin salts of N-(5-chlorosalicylidene)-α-amino acid 1～6 were synthesized by the reaction of triphenyltin chloride with in situ formed Schiff base, potassium salt of N-(5-chlorosalicylidene)- α-amino acid, and characterized by means of elemental analysis, IR and NMR spectra. The crystal structures of triphenyltin N-(5-chlorosalicylidene)valinate (3) and triphenyltin N-(5-chlorosalicylidene)-isoleucinate (5) were reported. The X-ray structures reveal that the tin atom is five-coordinated and adopts a polymeric trans-O₂SnC₃ trigonal bipyramidal configuration with the axial positions occupied by a carboxylate oxygen from the ligand and the phenolic oxygen of the ligand in an adjacent complex.

Key words: 5-chlorosalicylic aldehyde, α-amino acid, Schiff base, crystal structure, triphenyltin(IV)

Cite this article

TIAN Lai-Jin*^,a,LIU Xi-Cheng^a,MAO Wu-Tao^a
SUN Yu-Xi^a,LIU Xi-Jie^b,ZHOU Zheng-Yu,c. Synthesis and Structural Characterization of Triphenyltin N-(5-Chlorosalicylidene)-α-amino Carboxylates[J]. Chin. J. Org. Chem., 2007, 27(10): 1258-1263.

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三苯基锡N-(5-氯亚水杨基)-α-氨基酸酯的合成及结构表征

Synthesis and Structural Characterization of Triphenyltin N-(5-Chlorosalicylidene)-α-amino Carboxylates

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