Chin. J. Org. Chem. ›› 1988, Vol. 8 ›› Issue (1): 23-28. Previous Articles     Next Articles

烯胺酮与烯胺酯的交叉缩合反应

康国钧;卓金聪;龙玛;高振衡;章本礼   

  1. 南开大学化学系
  • 发布日期:1988-02-25

Study on cross-condensation of enamino-ketones with enamino-esters

KANG GUOJUN;ZHUO JINCONG;LONG MA;GAO ZHENHENG;ZHANG BENLI   

  • Published:1988-02-25

The [3C + 3C] cross-condensation reactions of enamino-ketones with enamino-esters in the presence of trifluoroacetic acid (TFA) gave Me 2-amino-4,6-dimethylbenzoates as main product. E.g., condensation of ketone I with ester II gave 26% benzoate III.

Key words: ESTERS, CONDENSATION REACTION, CROSSED IMMUNITY, KETONE, TRIFLUOROACETIC ACID, ENAMINES

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