Chin. J. Org. Chem. ›› 1990, Vol. 10 ›› Issue (2): 149-152. Previous Articles     Next Articles

Original Articles

氯化镍催化的醚的酰化开裂反应

丁新;刘国斌   

  1. 复旦大学化学系
  • 发布日期:1990-04-25

Acylative cleavage of ethers catalyzed by nickel chloride

DING XIN;LIU GUOBIN   

  • Published:1990-04-25

A wide variety of ethers are cleaved with acetyl chloride or acetic anhydride in the presence of nickel chloride as catalyst, giving the corresponding esters in moderate to good yields. E.g., stirring Bu2O with AcCl and NiCl2 at room temperature for 3.5 h gave 74% BuOAc.

Key words: ETHER, ESTERS, ACYL CHLORIDES, NICKEL CHLORIDE, ACYLATION, ACID ANHYDRIDE, CLEAVAGE REACTION

CLC Number: