Aminoalkylation of benzotriazole: Synthesis of secondary amines

Chin. J. Org. Chem. ›› 1992, Vol. 12 ›› Issue (2): 198-201. Previous Articles Next Articles

Original Articles

苯骈三氮唑的胺烷基化: 二级胺的合成

王瑾;许恒峰;周洵均;杜少斌

杭州大学化学系;浙江大学化学系

发布日期:1992-04-25

Aminoalkylation of benzotriazole: Synthesis of secondary amines

WANG JIN;XU HENGFENG;ZHOU XUNJUN;DU SHAOBIN

Published:1992-04-25

Abstract

Aminoalkylation of benzatriazole with 4-Me2NC6H4CHO and RNH2 (R = Ph, substituted Ph, a-naphthyl, b-naphthyl, 3-pyridyl) gave 63-87% adducts I, reduction of which with NaBH4 gave 48-92% 4-Me2NC6H4CH2NHR.

Key words: INFRARED SPECTROPHOTOMETRY, BENZALDEHYDE P, ELEMENTAL ANALYSIS, BENZENEMETHANAMINIUM, METHANAMINE P, SECONDARY AMINE, NMR SPECTROMETRY, METHANAMINE P, SODIUM BOROHYDRIDE

CLC Number:

O621

Cite this article

WANG JIN;XU HENGFENG;ZHOU XUNJUN;DU SHAOBIN. Aminoalkylation of benzotriazole: Synthesis of secondary amines[J]. Chin. J. Org. Chem., 1992, 12(2): 198-201.

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苯骈三氮唑的胺烷基化: 二级胺的合成

Aminoalkylation of benzotriazole: Synthesis of secondary amines

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