Synthesis of sterically hindered metalloporphyrins and their catalytic behaviour in the hydroxylation of n-hexane

Chin. J. Org. Chem. ›› 1992, Vol. 12 ›› Issue (2): 194-197. Previous Articles Next Articles

Original Articles

位阻型金属卟啉的合成及其催化烷烃基化的反应

郑维忠;曾庆平;王先元;李广年

中国科学院成都有机化学研究所;中国科学院上海有机化学研究所;中国科学院金属有机化学开放实验室

发布日期:1992-04-25

Synthesis of sterically hindered metalloporphyrins and their catalytic behaviour in the hydroxylation of n-hexane

ZHENG WEIZHONG;ZENG QINGPING;WANG XIANYUAN;LI GUANGNIAN

Published:1992-04-25

Abstract

A sterically hindered porphyrin, tetrakis(3,5-di-tert-butyl-4-methoxyphenyl)porphyrin (I), was synthesized by the reaction of 3,5-di-tert-butyl-4-methoxybenzaldehyde with pyrrole. Metal complexes were obtained from the reaction of metal ions with I. Hydroxylation reactions of n-hexane catalyzed by iron(III) porphyrins or manganese(III) porphyrins with iodosobenzene have also been investigated.

Key words: INFRARED SPECTROPHOTOMETRY, APPLICATION, IRON COMPLEX, ELEMENTAL ANALYSIS, NICKEL COMPLEX, NMR SPECTROMETRY, MANGANESE COMPLEX, ZINC COMPLEX, COPPER COMPLEX, COBALT COMPLEX

CLC Number:

O627

Cite this article

ZHENG WEIZHONG;ZENG QINGPING;WANG XIANYUAN;LI GUANGNIAN. Synthesis of sterically hindered metalloporphyrins and their catalytic behaviour in the hydroxylation of n-hexane[J]. Chin. J. Org. Chem., 1992, 12(2): 194-197.

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位阻型金属卟啉的合成及其催化烷烃基化的反应

Synthesis of sterically hindered metalloporphyrins and their catalytic behaviour in the hydroxylation of n-hexane

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