Studies on tri[(methyldiphenylsilyl)mehylene]tin carboxylates

Abstract

aryloxyacetates were synthesized by reaction of [(Ph2MeSiCH2)3Sn]2O with the corresponding carboxylic acids. The IR, 1H, 29Si and 119Sn NMR were determine The results of spectra data showed that these compounds are four-coordination organotin compounds For aryloxyacetates, there is a liner relationship between chem. shift of 119Sn NMR and Hammett constant( of para-substituent of the aryl groups.

Key words: CARBOXYLIC ACID ESTER, BIOLOGICAL ACTIVITY, SILANE P, ORGANO TIN COMPOUNDS, ACARICIDES

CLC Number:

O627

Cite this article

XIE QINGLAN;XU XIAOHUA;XIE XIAOJUAN;CHEN CHUANFENG. Studies on tri[(methyldiphenylsilyl)mehylene]tin carboxylates[J]. Chin. J. Org. Chem., 1993, 13(3): 264-268.

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