Synthesis and Properties of 2,3-Bis(benzylthiomethyl)- 6,7-bis(2-cyanoethylthio)tetrathiafulvalene

Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (02): 194-198. Previous Articles Next Articles

Original Articles

2,3-二硫苄基-6,7-二(2-氰基乙硫基)四硫富瓦烯的合成及其性质研究

朱玉兰*^,1,2 尹起范¹，盛振环¹,2，杨艳杰²，李锦莲²，卢然³

(¹淮阴师范学院化学系江苏省低维材料化学重点建设实验室淮安 223300)
(²延边大学理工学院化学系延吉 133002)
(³吉林大学化学学院长春 130023)

收稿日期:2004-08-31 修回日期:2005-08-04 发布日期:2006-01-21
通讯作者: 朱玉兰

Synthesis and Properties of 2,3-Bis(benzylthiomethyl)- 6,7-bis(2-cyanoethylthio)tetrathiafulvalene

ZHU Yu-Lan*^,1,2,YIN Qi-Fan¹,SHENG Zhen-Huan¹,2
YANG Yan-Jie²,LI Jin-Lian²,LU Ran³

(¹ Department of Chemistry, Huaiyin Teachers College, Jiangsu Key Laboratory for Chemistry of
Low-Dimensional Materials, Huaian 223300)
(² Department of Chemistry, Science and Engineering College, Yanbian University, Yanji 133002)
(³ Department of Chemistry, Jilin University, Changchun 130023)

Received:2004-08-31 Revised:2005-08-04 Published:2006-01-21
Contact: ZHU Yu-Lan

Abstract

2,3-Bis(benzylthiomethyl)-6,7-bis(2-cyanoethylthio)tetrathiafulvalene was synthesized and characterized by UV-Vis, ¹H NMR, IR, MS spectra and element analyses. Its behaviors were studied employing cyclic voltammetry (CV) method using Gaussian 98 quantum chemical program package, and the method of density functional theory (DFT) at the level of B3LYP/ 6-31G(d), to optimize molecular geometry structure. The results showed that with the introduction of substituents HOMO energy of the title compound becomes low. As a result, molecule tends to be stable, which is fit with the idea of design.

Key words: cyclic voltammetry, electronic spectrum, DFT, TTF derivative

Cite this article

ZHU Yu-Lan*^,1,2,YIN Qi-Fan,SHENG Zhen-Huan^1,2
YANG Yan-Jie²,LI Jin-Lian²,LU Ran^{3. Synthesis and Properties of 2,3-Bis(benzylthiomethyl)- 6,7-bis(2-cyanoethylthio)tetrathiafulvalene[J]. Chin. J. Org. Chem., 2006, 26(02): 194-198.}

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2,3-二硫苄基-6,7-二(2-氰基乙硫基)四硫富瓦烯的合成及其性质研究

Synthesis and Properties of 2,3-Bis(benzylthiomethyl)- 6,7-bis(2-cyanoethylthio)tetrathiafulvalene

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