Chin. J. Org. Chem. ›› 1998, Vol. 18 ›› Issue (1): 82-87. Previous Articles     Next Articles

Original Articles

无外加催化剂条件下芳香醛与活性亚甲基化合物的缩合反应和迈克尔加成反应

史达清;路再生;高原;冯友建;周龙虎;戴桂元   

  1. 徐州师范大学化学系
  • 发布日期:1998-02-25

Condensation and Michael addition reactions of aromatic aldehydes with acidic methylene compounds without catalyst

SHI DAQING;LU ZAISHENG;GAO YUAN;FENG YOUJIAN;ZHOU LONGHU;DAI GUIYUAN   

  • Published:1998-02-25

The reactions of aromatic aldehydes with acidic methylene compounds in DMF without catalyst were studied. The condensation reaction of aromatic aldehydes (1) with 2,2-dimethyl-1,3-dioxane-4,6- dione (2) afforded 2,2-dimethyl-5-arylmethylene-1,3-dioxane-4,6- dione (3a~f). However, treatment of aromatic aldehydes (1) with 5,5-dimethyl-1,3-cyclohexanedione (4) under the same conditions afforded 2,2'-arylmethylene bis(3-hydroxy-5,5-dimethyl-2-cyclohexen-1- one) (5a~h). The crystal structure of 5b was determined by X-ray diffraction analysis.

Key words: AROMATIC ALDEHYDE, CYCLOHEXANEDIONE P, CONDENSATION REACTION, DIOXANE P, MICHAEL ADDITION REACTION, METHYLENE, DIKETONE, CRYSTAL STRUCTURE DETERMINATION

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