Synthesis and characterization of Di - (or Tri) butyltin alkenyl (or alkynyl) phosphates

Abstract

Twelve new di - (or tri) butyltin alkenyl (or alkynyl) phosphates of general formular [(n - C4H9)nSn]n-1O2P(O) R (n=2,3; R= -CH = CClPh, - C ≡ CC5H11-n, - C ≡ CC6H13-n, - C≡CPh, C≡CCH2OMe, C≡CCH2OEt) were synthesized and characterized by elemental analysis, IR, ^1H NMR spectra and TG-DTA. The bioassay of some compounds showed that they had better miticidal activity and fungicidal activity.

Key words: PHOSPHONIC ACID ESTER, ORGANO TIN COMPOUNDS, INSECTICIDES, BIOLOGICAL ACTIVITY, ELEMENTAL ANALYSIS, INFRARED SPECTROPHOTOMETRY, NMR SPECTROMETRY, DIFFERENTIAL THERMAL ANALYSIS, THERMOGRAVIMETRY, STRUCTURE CHARACTERISTICS

CLC Number:

O657

Cite this article

Yin Handong;Ma Chunlin;Zhang Rufen. Synthesis and characterization of Di - (or Tri) butyltin alkenyl (or alkynyl) phosphates[J]. Chin. J. Org. Chem., 2000, 20(1): 108-111.

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