Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (05): 627-642. Previous Articles     Next Articles

Review

寡糖的立体选择性合成策略

陈朗秋*,1,2,赖端1,宋志伟1,赵兴俄1 孔繁祚*,2   

  1. (1湘潭大学化学学院 湘潭 411105)
    (2中国科学院生态环境研究中心 北京 100085)
  • 收稿日期:2005-08-02 修回日期:2005-10-27 发布日期:2006-04-28
  • 通讯作者: 孔繁祚

Strategies on Stereoselective Synthesis of Oligosaccharides

CHEN Lang-Qiu*,1,2,LAI Duan1, SONG Zhi-Wei1
ZHAO Xing-E1,KONG Fan-Zuo*,2   

  1. (1 Institute of Chemistry, Xiangtan University, Xiangtan 411105)
    (2 Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085)
  • Received:2005-08-02 Revised:2005-10-27 Published:2006-04-28
  • Contact: KONG Fan-Zuo

Researches on biological activity of oligosaccharides and their complexes are of important biogical significance. It is very important to synthesize special α or/and β glycoside in order to synthesize complicated oligosaccharides and their complexes by chemical strategies. Up to nowadays, studies on strategies of chemical stereoselective design and synthesis of oligosaccharides and their complexes have been regarded as one of the most remarkable fields in glycochemistry, and have been paid much attention. This review describes the development of highly stereoselective synthesis of oligosac-charides decades.

Key words: stereo-selectivity, neighboring group participation, intramolecular aglycon delivery, oligosaccharide synthesis