Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (04): 506-514. Previous Articles     Next Articles

Reviews

铱催化环加成反应的研究进展

边红旭,杨定乔   

  1. (华南师范大学化学与环境学院 广州 510006)
  • 收稿日期:2009-03-30 修回日期:2009-06-27 发布日期:2010-04-28
  • 通讯作者: 杨定乔 E-mail:yangdq@scnu.edu.cn,zqwlh@126.com
  • 基金资助:

    国家级.国家自然科学基金

Progress of Iridium-Catalyzed Cycloaddition Reactions

Bian Hongxu Yang Dingqiao   

  1. (School of Chemistry and Environment, South China Normal University, Guangzhou 51006)
  • Received:2009-03-30 Revised:2009-06-27 Published:2010-04-28
  • Contact: Yang Ding-qiao E-mail:yangdq@scnu.edu.cn,zqwlh@126.com

Transition metal-catalyzed cycloaddition reaction of unsaturated substances, such as alkynes and alkenes, is one of the most important methods for the synthesis of mono-ring and multi-ring systems. In this paper, the recent progress in iridium-catalyzed cycloaddition reactions is reviewed, mainly including [2+ 2+1], [2+2+2], [4+2], 1,3-dipolar cycloaddition reactions. In addition, some iridium-catalyzed [3+2+2], [3+2] and [5+1] cycloaddition reactions are described. Some parts of cycloaddition reaction mechanisms are also discussed.

Key words: iridium catalysis, cycloaddition, iridium complex