Differential Study on the Electronic Effect of Chloro-substituent in Benzene Ring in Ionic Liquids

Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (05): 753-756. Previous Articles Next Articles

Notes

在离子液体体系中苯环上氯取代基电子效应差异性研究

吴建一*^{,1,2，向自伟²，宗乾收¹，缪程平¹，邹玲²}

(¹嘉兴学院生物与化学工程学院嘉兴 314001)
(²常州大学化学化工学院常州 213164 )

收稿日期:2009-05-15 修回日期:2009-10-30 发布日期:2009-12-22
通讯作者: 吴建一 E-mail:jianyi_wu@163.com
基金资助:
浙江省自然基金

Differential Study on the Electronic Effect of Chloro-substituent in Benzene Ring in Ionic Liquids

Wu Jianyi*^,1,2 Xiang Ziwei² Zong Qianshou¹ Miao Chengpin¹ Zou Ling²

(¹ College of Biology and Chemical Engineering, Jiaxing University, Jiaxing 314001)
(² Department of Chemical Engineering, Changzhou University, Changzhou 213614)

Received:2009-05-15 Revised:2009-10-30 Published:2009-12-22
Contact: Jian-Yi Wu E-mail:jianyi_wu@163.com

Abstract

Nucleophilic substitution of various substitutents of phenoxyl anion with isopropylbromide and nucleophilic addition reaction of different substitutents of benzaldehyde to carbamide and ethyl acetoacetate were conducted in [BMim]BF₄ ionic liquids. The results indicated that the chlorine atom was an activating group. It has been obtained by analysis that the benzene ring of the reactant may form the big multi-layered π complex structure with the heteroaromatic ring of ionic liquids which influenced the normal formation of solvent effect formation and formed the unique ion-sphere solvent effect.

Key words: ionic liquid, substituted group, electronic effect, solvent effect

Cite this article

WU Jian-Yi, XIANG Zi-Wei, ZONG Qian-Shou, MIAO Cheng-Ping, ZOU Ling. Differential Study on the Electronic Effect of Chloro-substituent in Benzene Ring in Ionic Liquids[J]. Chin. J. Org. Chem., 2010, 30(05): 753-756.

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在离子液体体系中苯环上氯取代基电子效应差异性研究

Differential Study on the Electronic Effect of Chloro-substituent in Benzene Ring in Ionic Liquids

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